Asymmetric Alkynylation of Aldehydes Catalyzed by Bifunctional Zinc(salen) Complex
文献类型：期刊论文
| 作者 | Shen Chun1,2; Chen Lei1; Tang Jie2; Xu Minghua1
|
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2009-02 |
| 卷号 | 27期号:2页码:413-418 |
| 关键词 | asymmetric alkynylation bifunctional catalyst salen |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.200990068 |
| 文献子类 | Article |
| 英文摘要 | The asymmetric alkynylation of aldehydes catalyzed by bifunctional Zn(salen) catalyst was realized. With a Kozlowski salen ligand (7e) bearing secondary basic 1-piperidinylmethyl groups at C-3 and C-3', the enhanced catalytic reactivity and stereoselectivity in comparison with that of normal salen ligands in the alkynylzinc addition to aldehydes were observed. |
| WOS关键词 | ENANTIOSELECTIVE PHENYLACETYLENE ADDITION ; ALCOHOL-TITANIUM COMPLEX ; AROMATIC-ALDEHYDES ; ALKYNE ADDITIONS ; GAMMA-HYDROXY-ALPHA,BETA-ACETYLENIC ESTERS ; ALKYNYLZINC ADDITION ; ORGANOZINC REAGENTS ; ALPHA-KETOESTERS ; TERMINAL ALKYNES ; KETONES |
| 资助项目 | Chinese Academy of Sciences[00000000] ; National Natural Science Foundation of China[00000000] ; Shanghai Institute of Materia Medica[00000000] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3630613 |
| WOS记录号 | WOS:000265281300033 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/279327]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Xu Minghua |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China; 2.E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen Chun,Chen Lei,Tang Jie,et al. Asymmetric Alkynylation of Aldehydes Catalyzed by Bifunctional Zinc(salen) Complex[J]. CHINESE JOURNAL OF CHEMISTRY,2009,27(2):413-418. |
| APA | Shen Chun,Chen Lei,Tang Jie,&Xu Minghua.(2009).Asymmetric Alkynylation of Aldehydes Catalyzed by Bifunctional Zinc(salen) Complex.CHINESE JOURNAL OF CHEMISTRY,27(2),413-418. |
| MLA | Shen Chun,et al."Asymmetric Alkynylation of Aldehydes Catalyzed by Bifunctional Zinc(salen) Complex".CHINESE JOURNAL OF CHEMISTRY 27.2(2009):413-418. |
入库方式： OAI收割
来源：上海药物研究所
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