Copper-Mediated Diastereoselective C-H Thiolation of Ferrocenes
文献类型：期刊论文
| 作者 | Kong, Wei-Jun2; Shao, Qian2; Li, Ming-Hong2; Zhou, Zeng-Le2; Xu, Hui1; Dai, Hui-Xiong1,2 ; Yu, Jin-Quan2,3
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| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2018-09-10 |
| 卷号 | 37期号:17页码:2832-2836 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/acs.organomet.8b00457 |
| 文献子类 | Article |
| 英文摘要 | The first copper-mediated diastereoselective C-H thiolation of ferrocenes has been developed. A chiral oxazoline directing group with tert-butyl substituent is essential to the high diastereoselectivity ratio and the suppression of overreaction of monothiolated products. This reaction tolerated various functional groups on arylthiols, implying its potential application in N,S-bidentate planar chiral ligands. |
| WOS关键词 | PLANAR-CHIRAL FERROCENES ; ASYMMETRIC-SYNTHESIS ; ENANTIOSELECTIVE SYNTHESIS ; KINETIC RESOLUTION ; STEREOSELECTIVE-SYNTHESIS ; BOND FUNCTIONALIZATION ; SANDWICH COMPOUNDS ; ALLYLIC OXIDATION ; ORTHO-LITHIATION ; DIRECTING GROUP |
| 资助项目 | Shanghai Institute of Materia Medica, Chinese Academy of Sciences[00000000] ; Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences[00000000] ; NSFC[21472211] ; NSFC[21502212] ; NSFC[21772211] ; Youth Innovation Promotion Association CAS[2014229] ; Youth Innovation Promotion Association CAS[2018293] ; Institutes for Drug Discovery and Development, Chinese Academy of Sciences[CASIMM 0120163006] ; Science and Technology Commission of Shanghai Municipality[17JC1405000] ; NSF under the CCI Center for Selective C-H Functionalization[CHE-1205646] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000444527200002 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/279582]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Dai, Hui-Xiong; Yu, Jin-Quan |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, Dept Med Chem, 555 Rd Chong Zhi,Zhangjiang Hitech Pk, Shanghai 201203, Peoples R China; 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 20032, Peoples R China; 3.Scripps Res Inst, Dept Chem, 10550 N Torrey Pines Rd, La Jolla, CA 92037 USA |
| 推荐引用方式 GB/T 7714 | Kong, Wei-Jun,Shao, Qian,Li, Ming-Hong,et al. Copper-Mediated Diastereoselective C-H Thiolation of Ferrocenes[J]. ORGANOMETALLICS,2018,37(17):2832-2836. |
| APA | Kong, Wei-Jun.,Shao, Qian.,Li, Ming-Hong.,Zhou, Zeng-Le.,Xu, Hui.,...&Yu, Jin-Quan.(2018).Copper-Mediated Diastereoselective C-H Thiolation of Ferrocenes.ORGANOMETALLICS,37(17),2832-2836. |
| MLA | Kong, Wei-Jun,et al."Copper-Mediated Diastereoselective C-H Thiolation of Ferrocenes".ORGANOMETALLICS 37.17(2018):2832-2836. |
入库方式： OAI收割
来源：上海药物研究所
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