Palladium-Catalyzed Formylation of Aryl Iodides with HCOOH as CO Source
文献类型：期刊论文
| 作者 | Sun, Guanglong2,3; Lv, Xue2,3; Zhang, Yinan1; Lei, Min2,3 ; Hu, Lihong1
|
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-08-18 |
| 卷号 | 19期号:16页码:4235-4238 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.7b01882 |
| 文献子类 | Article |
| 英文摘要 | A facile and practical method for the synthesis of aromatic aldehydes by palladium-catalyied reductive carbonylation starting from aryl iodides and HCOOH is described. Compared to the known formylation procedure, HCOOH serves not only as the most Convenient and environmental friendly Cl source but also as the reviving agent in the reductive elimination process of Pd-catalyst. Furthermore, this procedure is also apPlied successfully to modifitation of natural prochicts, such as vindoline, tabersonin, and viricamine, to obtain the corresponding products in good yields. |
| WOS关键词 | REDUCTIVE CARBONYLATION ; VINYLIC HALIDES ; FORMIC-ACID ; REGIOSELECTIVE HYDROFORMYLATION ; COUPLING REACTIONS ; N-FORMYLSACCHARIN ; AROMATIC IODIDES ; INDOLE ALKALOIDS ; H ARYLATION ; ALDEHYDES |
| 资助项目 | National Natural Science Foundation of China[81473110] ; National Natural Science Foundation of China[81561148011] ; Special Fund for Strategic Pilot Technology Chinese Academy of Sciences[XDA12040303] ; Science Foundation of Shanghai[15431901100] ; Priority Academic Program Development of Jiangsu Higher Education Institutions[00000000] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000408285600021 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/272525]  |
| 专题 | 上海中药现代化研究中心 |
| 通讯作者 | Lei, Min; Hu, Lihong |
| 作者单位 | 1.Nanjing Univ Chinese Med, Stake Key Lab Cultivat Base TCM Qual & Efficacy, Jiangsu Collaborat Innovat Ctr Chinese Med Resour, Jiangsu Key Lab Funct Subst Chinese Med,Sch Pharm, Nanjing, Jiangsu, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Guanglong,Lv, Xue,Zhang, Yinan,et al. Palladium-Catalyzed Formylation of Aryl Iodides with HCOOH as CO Source[J]. ORGANIC LETTERS,2017,19(16):4235-4238. |
| APA | Sun, Guanglong,Lv, Xue,Zhang, Yinan,Lei, Min,&Hu, Lihong.(2017).Palladium-Catalyzed Formylation of Aryl Iodides with HCOOH as CO Source.ORGANIC LETTERS,19(16),4235-4238. |
| MLA | Sun, Guanglong,et al."Palladium-Catalyzed Formylation of Aryl Iodides with HCOOH as CO Source".ORGANIC LETTERS 19.16(2017):4235-4238. |
入库方式： OAI收割
来源：上海药物研究所
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