Rh-catalyzed intramolecular aromatic C-H insertion of alpha-diazo beta-ketoesters: synthesis of 4-carbonyl chroman derivatives
文献类型：期刊论文
| 作者 | Zhang, Xiaolin; Lei, Mei; Zhang, Yi-Nan; Hu, Li-Hong |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2014-05-27 |
| 卷号 | 70期号:21页码:3400-3406 |
| 关键词 | C-H insertion Diazo compounds Synthetic methods Heterocycles |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2014.03.093 |
| 文献子类 | Article |
| 英文摘要 | A Rh-catalyzed intramolecular aromatic C-H insertion of alpha-diazo beta-ketoesters was developed. This protocol offers a practical strategy for the synthesis of 4-carbonyl chroman derivatives with high yield and is compatible with a wide variety of substituents. Synthetic applications of the 4-carbonyl chroman were also demonstrated. (C) 2014 Elsevier Ltd. All rights reserved. |
| WOS关键词 | CATIONIC CARBOXYLATO COMPLEXES ; OXO THIOETHERS ; REARRANGEMENT ; DIRHODIUM(II) ; OXIDATION ; DEGUELIN |
| 资助项目 | National Natural Science Foundation of China[81273397] ; Chinese National Science & Technology Major Project 'Key New Drug Creation and Manufacturing Program'[2013ZX09508104] ; Chinese National Science & Technology Major Project 'Key New Drug Creation and Manufacturing Program'[2012ZX09103-101-018] ; Chinese National Science & Technology Major Project 'Key New Drug Creation and Manufacturing Program'[2014ZX09301-306-03] ; Science Foundation of Shanghai[12XD1405700] ; Basic and Advanced Technology Research Project in Henan Province[122300410004] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000335805000004 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277068]  |
| 专题 | 上海中药现代化研究中心 |
| 通讯作者 | Zhang, Yi-Nan |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai Res Ctr Modernizat Tradit Chinese Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xiaolin,Lei, Mei,Zhang, Yi-Nan,et al. Rh-catalyzed intramolecular aromatic C-H insertion of alpha-diazo beta-ketoesters: synthesis of 4-carbonyl chroman derivatives[J]. TETRAHEDRON,2014,70(21):3400-3406. |
| APA | Zhang, Xiaolin,Lei, Mei,Zhang, Yi-Nan,&Hu, Li-Hong.(2014).Rh-catalyzed intramolecular aromatic C-H insertion of alpha-diazo beta-ketoesters: synthesis of 4-carbonyl chroman derivatives.TETRAHEDRON,70(21),3400-3406. |
| MLA | Zhang, Xiaolin,et al."Rh-catalyzed intramolecular aromatic C-H insertion of alpha-diazo beta-ketoesters: synthesis of 4-carbonyl chroman derivatives".TETRAHEDRON 70.21(2014):3400-3406. |
入库方式： OAI收割
来源：上海药物研究所
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