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Divergent synthesis of N-heterocycles by Pd-catalyzed controllable cyclization of vinylethylene carbonates

文献类型：期刊论文

作者Yang, Yuwen1; Yang, Weibo1,2,3
刊名CHEMICAL COMMUNICATIONS
出版日期2018-11-07
卷号54期号:86页码:12182-12185
ISSN号1359-7345
DOI10.1039/c8cc06945j
文献子类Article
英文摘要Here, we report a palladium-catalyzed controllable cyclization of vinyl ethylene carbonates that proceeds through formal migration [2+3] and [5+2] cycloadditions, respectively, under mild conditions. The transformation described here affords a series of synthetically versatile 5,7-membered N-heterocycles which are found in natural products and pharmaceuticals with biological and medicinal properties.
WOS关键词ASYMMETRIC DECARBOXYLATIVE CYCLOADDITION ; NITROGEN-HETEROCYCLES ; ENANTIOSELECTIVE CONSTRUCTION ; QUATERNARY STEREOCENTERS ; ALLYLIC SUBSTITUTION ; PALLADIUM ; BOND ; WATER ; CARBONYLATION ; ALKYLATIONS
资助项目100 talent program of Chinese Academy of Sciences[00000000] ; Chinese NSF[21702217] ; 1000-Youth Talents Plan[00000000] ; Shanghai-Technology Innovation Action Plan[18JC1415300]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000448501400008
出版者ROYAL SOC CHEMISTRY
源URL[http://119.78.100.183/handle/2S10ELR8/279497]  
专题分子影像中心（筹）
通讯作者Yang, Weibo
作者单位1.Chinese Acad Sci, Shanghai Inst Mat Med, Key Lab Receptor Res, Shanghai, Peoples R China;
2.Univ Sci & Technol Liaoning, Educ Dept Liaoning Prov, Key Lab Funct Mat, Anshan 114051, Peoples R China
3.Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Mat Med, Dept Med Chem, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China;
推荐引用方式
GB/T 7714		 Yang, Yuwen,Yang, Weibo. Divergent synthesis of N-heterocycles by Pd-catalyzed controllable cyclization of vinylethylene carbonates[J]. CHEMICAL COMMUNICATIONS,2018,54(86):12182-12185.
APA Yang, Yuwen,&Yang, Weibo.(2018).Divergent synthesis of N-heterocycles by Pd-catalyzed controllable cyclization of vinylethylene carbonates.CHEMICAL COMMUNICATIONS,54(86),12182-12185.
MLA Yang, Yuwen,et al."Divergent synthesis of N-heterocycles by Pd-catalyzed controllable cyclization of vinylethylene carbonates".CHEMICAL COMMUNICATIONS 54.86(2018):12182-12185.

入库方式： OAI收割

来源：上海药物研究所

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