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UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units
文献类型：期刊论文
| 作者 | Wang Li; Pan Shilie ; Chang Lixian; Hu Jianyang; Yu Hongwei; Pan, SL
|
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 51期号:3页码:1852-1858 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic2021337 |
| 英文摘要 | A new noncentrosymmetric polyborate, Ba-2[B6O9(OH)(4)], has been synthesized under a hydrothermal condition. The polyborate contains chiral layers constructed by two kinds of helical chains and also form new B18O42 circles based on B3O8 units [(3: Delta+2T)]. One kind of Ba atom locates in the cavity surrounded by the B11O11 ring within the anion layer, and the other kind of Ba atom inserts between two adjacent layers. UV-vis diffuse reflectance spectroscopy demonstrates that the compound has a cutoff edge below 190 nm and has a large second-harmonic generation (SHG) effect, which is approximately 3 times that of KH2PO4 (KDP) and is type-I phase matchable. |
| 学科主题 | Chemistry |
| WOS记录号 | WOS:000300474700078 |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1638]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
| 通讯作者 | Pan, SL |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Li,Pan Shilie,Chang Lixian,et al. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units[J]. INORGANIC CHEMISTRY,2012,51(3):1852-1858. |
| APA | Wang Li,Pan Shilie,Chang Lixian,Hu Jianyang,Yu Hongwei,&Pan, SL.(2012).UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units.INORGANIC CHEMISTRY,51(3),1852-1858. |
| MLA | Wang Li,et al."UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units".INORGANIC CHEMISTRY 51.3(2012):1852-1858. |
入库方式： OAI收割
来源：新疆理化技术研究所
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