Metal Ionic Liquids Produce Metal-Dispersed Carbon-Nitrogen Networks for Efficient CO2 Electroreduction
文献类型：期刊论文
| 作者 | Cheng, Xiuyan2,3; Tan, Dongxing2,3; Zeng, Shaojuan4; Zhang, Xiangping4; Tan, Xiuniang2,3; Shi, Jinbiao2,3; Zhang, Bingxing2,3; Zheng, Lirong1; Zhang, Fanyu2,3; Feng, Jiaqi4 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2019-07-18 |
| 卷号 | 11期号:14页码:3166-3170 |
| 关键词 | metal ionic liquid CO2 reduction coordination electrocatalyst |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.201900615 |
| 英文摘要 | To develop novel strategies for fabricating metal carbon-based materials with desirable compositions and structures for catalysis is of great importance. Here we propose for the first time the utilization of metal ionic liquid as a precursor for the synthesis of metal carbon-based materials through a one-step pyrolysis route. The method produces the metal dispersed cross-linked carbon framework with a highly mesoporous structure. Such a Ni/C-N catalyst exhibits outstanding electrocatalytic activity for CO2 reduction reaction, i. e., an excellent CO faradaic efficiency of approximately 94 % at an potential of -0.75 V (versus the reversible hydrogen electrode). The method proposed in this work is simple, convenient, low-cost, adjustable and versatile for the synthesis of different kinds of M/C-N materials because the structures and properties of metal ionic liquids can be easily designed and tuned by changing the anions and cations. |
| WOS关键词 | REDUCTION ; CATALYSIS ; SITES |
| 资助项目 | National Natural Science Foundation of China[21525316] ; National Natural Science Foundation of China[21673254] ; Ministry of Science and Technology of China[2017YFA0403003] ; Chinese Academy of Sciences[QYZDY-SSW-SLH013] ; Beijing Municipal Science & Technology Commission[Z181100004218004] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000477986300004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Chinese Academy of Sciences ; Beijing Municipal Science & Technology Commission |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30319]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Jianling |
| 作者单位 | 1.Chinese Acad Sci, BSRF, Inst High Energy Phys, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 5.Huairou Natl Comprehens Sci Ctr, Phys Sci Lab, Beijing 101400, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Xiuyan,Tan, Dongxing,Zeng, Shaojuan,et al. Metal Ionic Liquids Produce Metal-Dispersed Carbon-Nitrogen Networks for Efficient CO2 Electroreduction[J]. CHEMCATCHEM,2019,11(14):3166-3170. |
| APA | Cheng, Xiuyan.,Tan, Dongxing.,Zeng, Shaojuan.,Zhang, Xiangping.,Tan, Xiuniang.,...&Zhang, Jianling.(2019).Metal Ionic Liquids Produce Metal-Dispersed Carbon-Nitrogen Networks for Efficient CO2 Electroreduction.CHEMCATCHEM,11(14),3166-3170. |
| MLA | Cheng, Xiuyan,et al."Metal Ionic Liquids Produce Metal-Dispersed Carbon-Nitrogen Networks for Efficient CO2 Electroreduction".CHEMCATCHEM 11.14(2019):3166-3170. |
入库方式： OAI收割
来源：过程工程研究所
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