Hollow Multi-Shelled Structural TiO2-x with Multiple Spatial Confinement for Long-Life Lithium-Sulfur Batteries
文献类型：期刊论文
| 作者 | Salhabi, Esmail Husein M.1,2; Zhao, Jilu1,2; Wang, Jiangyan1; Yang, Mei1,2; Wang, Bao1,2; Wang, Dan1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019-07-01 |
| 卷号 | 58期号:27页码:9078-9082 |
| 关键词 | hollow multi-shelled structures (HoMSs) Li-S batteries polysulfides titanium |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201903295 |
| 英文摘要 | TiO2-x with well-controlled hollow multi-shelled structures (HoMSs) were designed and synthesized, via a sequential templating approach (STA), to act as sulfur carrier materials. They were explored as physico-chemical encapsulation materials. Particularly, the sulfur cathode based on triple-shelled TiO2-x HoMSs delivered a specific capacity of 903 mAh g(-1) with a capacity retention of 79% at 0.5 C and a Coulombic efficiency of 97.5% over 1000 cycles. The outstanding electrochemical performance is attributed to better spatial confinement and integrated conductivity of the intact triple-shell that combine the features of physico-chemical adsorption, short charge transfer path along with mechanical strength. |
| WOS关键词 | ANATASE TIO2 ; PERFORMANCE ; MICROSPHERES ; POLYSULFIDE ; COMPOSITES ; ELECTRODE ; CAPACITY ; CATHODE ; SPHERES ; ANODES |
| 资助项目 | Ministry of Education-Saudi Arabia ; National Natural Science Foundation of China[21590795] ; National Natural Science Foundation of China[21820102002] ; National Key Research and Development Program of China[2016YFB0600903] ; Chinese Academy of Sciences (CAS) Interdisciplinary Innovation Team ; Youth Innovation Promotion Association of CAS[2017070] ; Foundation for State Key Laboratory of Biochemical Engineering |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000476691200018 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | Ministry of Education-Saudi Arabia ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; Chinese Academy of Sciences (CAS) Interdisciplinary Innovation Team ; Youth Innovation Promotion Association of CAS ; Foundation for State Key Laboratory of Biochemical Engineering |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30416]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Dan |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Chinese Acad Sci, 19A Yuquanlu, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Salhabi, Esmail Husein M.,Zhao, Jilu,Wang, Jiangyan,et al. Hollow Multi-Shelled Structural TiO2-x with Multiple Spatial Confinement for Long-Life Lithium-Sulfur Batteries[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(27):9078-9082. |
| APA | Salhabi, Esmail Husein M.,Zhao, Jilu,Wang, Jiangyan,Yang, Mei,Wang, Bao,&Wang, Dan.(2019).Hollow Multi-Shelled Structural TiO2-x with Multiple Spatial Confinement for Long-Life Lithium-Sulfur Batteries.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(27),9078-9082. |
| MLA | Salhabi, Esmail Husein M.,et al."Hollow Multi-Shelled Structural TiO2-x with Multiple Spatial Confinement for Long-Life Lithium-Sulfur Batteries".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.27(2019):9078-9082. |
入库方式： OAI收割
来源：过程工程研究所
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