High Aluminum Content Beta Zeolite as an Active Lewis Acid Catalyst for gamma-Valerolactone Decarboxylation
文献类型：期刊论文
| 作者 | Wang, Xue1,2; Zeng, Jing1; Lu, Xingmei2,3; Xin, Jiayu2,3; Zhang, Suojiang2,3 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2019-07-10 |
| 卷号 | 58期号:27页码:11841-11848 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.9b01604 |
| 英文摘要 | Butene plays an essential role in the area of petrochemical industry. The production of butene from the biomass-derived platform molecule gamma-valerolactone (GVL) is of great interest. GVL decarboxylation reaction occurred under high temperature because the catalytic activity of the catalysts used before was not efficient for this reaction. In this work, beta zeolite with Si:Al = 5 was synthesized and used for GVL decarboxylation. It exhibited a higher catalytic performance than other commercial zeolites due to a large number of Lewis acid sites and relatively large micropore size. At 300 degrees C, 99.5% GVL conversion and 98% butene yield were obtained after condition optimizing. For further research, the influence of the Bronsted/Lewis acid ratio was investigated, and it turned out that Lewis acid was more active than Bronsted acid in crystalline material on GVL decarboxylation for the first time. |
| WOS关键词 | LEVULINIC ACID ; BIOMASS ; CONVERSION ; FUELS ; ALKYLATION ; HYDROCARBONS ; SELECTIVITY ; ISOBUTANE ; 1-BUTENE ; ALKANES |
| 资助项目 | National Key R&D Program of China[2018YFB1501600] ; National Natural Science Foundation of China[21878314] ; National Natural Science Foundation of China[21878292] ; National Natural Science Foundation of China[21576269] ; National Natural Science Foundation of China[21476234] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000475537000023 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30471]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xin, Jiayu; Zhang, Suojiang |
| 作者单位 | 1.Shenyang Normal Univ, Sch Chem & Chem Engn, Shenyang 110034, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem & Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xue,Zeng, Jing,Lu, Xingmei,et al. High Aluminum Content Beta Zeolite as an Active Lewis Acid Catalyst for gamma-Valerolactone Decarboxylation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(27):11841-11848. |
| APA | Wang, Xue,Zeng, Jing,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2019).High Aluminum Content Beta Zeolite as an Active Lewis Acid Catalyst for gamma-Valerolactone Decarboxylation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(27),11841-11848. |
| MLA | Wang, Xue,et al."High Aluminum Content Beta Zeolite as an Active Lewis Acid Catalyst for gamma-Valerolactone Decarboxylation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.27(2019):11841-11848. |
入库方式： OAI收割
来源：过程工程研究所
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