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A facile synthesis of nitrogen-doped hierarchical porous carbon with hollow sphere structure for high-performance supercapacitors

文献类型：期刊论文

作者Shang, Yunpeng2; Hu, Xudong2,4; Li, Xin2,4; Cai, Shu2; Liang, Guangchuan1; Zhao, Junmei5; Zheng, Chunming3,4; Sun, Xiaohong2,4
刊名JOURNAL OF MATERIALS SCIENCE
出版日期2019-10-01
卷号54期号:19页码:12747-12757
ISSN号0022-2461
DOI10.1007/s10853-019-03744-w
英文摘要In this work, nitrogen-doped carbon with hierarchical porous and hollow sphere structure has been synthesized through a simple and facile route of spray drying using glycine as the nitrogen-containing carbon source. After KOH activation, the prepared material (NHPCA) shows a large specific surface area of 962m(2)g(-1) with moderate N-doping of 5.74% and exhibits a high specific capacitance of 271Fg(-1) in 6M KOH electrolyte at 1.0Ag(-1), remarkable rate capability and particularly stable cycling performance with no significant specific capacitance drop after 10000 cycles at 1.0Ag(-1). The excellent electrochemical properties come from the unique structure and the doping of nitrogen. The hierarchical pore structure improves the efficiency of electrolyte ions transport, and diffusion and the hollow sphere structure further facilitates mass transport. The doping of nitrogen increases the total capacitance by providing redox pseudo-capacitance. The results indicate the as-prepared nitrogen-doped carbon with hierarchical porous and hollow sphere structure can be used as a hopeful candidate for an efficient electrode of commercial supercapacitors devices.
WOS关键词TEMPLATE CARBONIZATION METHOD ; ELECTRODE MATERIALS ; HIGH-CAPACITY ; PHENOLIC RESIN ; ANODE MATERIAL ; HIGH-ENERGY ; SURFACE ; WASTE ; NANOSHEETS ; COMPOSITE
资助项目National Natural Science Foundation of China, NSFC[51772205] ; National Natural Science Foundation of China, NSFC[51572192] ; National Natural Science Foundation of China, NSFC[51772208] ; National Natural Science Foundation of China, NSFC[51472179] ; General Program of Municipal Natural Science Foundation of Tianjin[17JCYBJC17000] ; General Program of Municipal Natural Science Foundation of Tianjin[17JCYBJC22700]
WOS研究方向Materials Science
语种英语
出版者SPRINGER
WOS记录号WOS:000475764300039
资助机构National Natural Science Foundation of China, NSFC ; General Program of Municipal Natural Science Foundation of Tianjin
源URL[http://ir.ipe.ac.cn/handle/122111/30500]  
专题中国科学院过程工程研究所
通讯作者Zheng, Chunming; Sun, Xiaohong
作者单位1.Hebei Univ Technol, Inst Power Source & Ecomat Sci, Tianjin 300130, Peoples R China
2.Tianjin Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Adv Ceram & Machining Technol, Tianjin 300072, Peoples R China
3.Tianjin Polytech Univ, Sch Environm & Chem Engn, State Key Lab Hollow Fiber Membrane Mat & Membran, Tianjin 300387, Peoples R China
4.Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
5.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Shang, Yunpeng,Hu, Xudong,Li, Xin,et al. A facile synthesis of nitrogen-doped hierarchical porous carbon with hollow sphere structure for high-performance supercapacitors[J]. JOURNAL OF MATERIALS SCIENCE,2019,54(19):12747-12757.
APA Shang, Yunpeng.,Hu, Xudong.,Li, Xin.,Cai, Shu.,Liang, Guangchuan.,...&Sun, Xiaohong.(2019).A facile synthesis of nitrogen-doped hierarchical porous carbon with hollow sphere structure for high-performance supercapacitors.JOURNAL OF MATERIALS SCIENCE,54(19),12747-12757.
MLA Shang, Yunpeng,et al."A facile synthesis of nitrogen-doped hierarchical porous carbon with hollow sphere structure for high-performance supercapacitors".JOURNAL OF MATERIALS SCIENCE 54.19(2019):12747-12757.

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来源：过程工程研究所

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