Efficient Removal of Fluoride by Complexation Extraction: Mechanism and Thermodynamics
文献类型：期刊论文
| 作者 | Li, Jian1,2,3; Zhang, Hui1,2; Zhang, Jingjing1,2,3; Xiao, Qinggui1,2; Du, Xuan1,2; Qi, Tao1,2 |
| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2019-08-06 |
| 卷号 | 53期号:15页码:9102-9108 |
| ISSN号 | 0013-936X |
| DOI | 10.1021/acs.est.9b02369 |
| 英文摘要 | A complexation extraction system was designed to develop a new process for the efficient removal of fluoride from solutions, such as zinc or copper electrolytes or wastewater derived from flue gas. The effects of the boron fluoride molar ratio, organic phase composition, initial pH, temperature, and phase volume ratio on the extraction efficiency were investigated. The extraction efficiency was found to increase with the increase in the boron fluoride molar ratio, Alamine336 concentration, and phase volume ratio, whereas it decreased with the increase in temperature. For the simulated electrolyte or wastewater derived from flue gas, the majority of metallic ions were insensitive to the extraction, with the exception of Al3+ and Fe3+. Fluoride decreased from 5 g/L to 0.05 g/L after two-stage cross-flow extraction alone; with an extraction efficiency of 99%. Both the stripping and cycling properties were excellent when sodium hydroxide was employed as the stripping reagent. Furthermore, the loading capacity was 43.4 g/L, and increased by four times, when boric acid was added. This novel process implies a wide range of potential applications, such as the removal of unwanted fluoride ions from various high-fluoride polluted solutions and the simplification of brine phase diagram. |
| WOS关键词 | AQUEOUS-SOLUTIONS ; ANIONS ; NANOCOMPOSITE ; WATER ; ACID |
| 资助项目 | Key Research Program of the Frontier Sciences of CAS[QYZDJ-SSW-JSC021] ; Science and Technology Cooperation for Yunnan Provinces[2016IB002] ; CAS[2016IB002] ; Science and Technology Service Network Initiative of CAS[KFJ-SW-STS-148] ; Science and Technology Service Network Initiative of CAS[KFJ-STS-QYZD-011] ; National Natural Science Foundation of China[21506233] ; National Natural Science Foundation of China[51402303] ; National Natural Science Foundation of China[21606241] ; National Natural Science Foundation of China[51374191] |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000480370600065 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Key Research Program of the Frontier Sciences of CAS ; Science and Technology Cooperation for Yunnan Provinces ; CAS ; Science and Technology Service Network Initiative of CAS ; National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30578]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Hui |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jian,Zhang, Hui,Zhang, Jingjing,et al. Efficient Removal of Fluoride by Complexation Extraction: Mechanism and Thermodynamics[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2019,53(15):9102-9108. |
| APA | Li, Jian,Zhang, Hui,Zhang, Jingjing,Xiao, Qinggui,Du, Xuan,&Qi, Tao.(2019).Efficient Removal of Fluoride by Complexation Extraction: Mechanism and Thermodynamics.ENVIRONMENTAL SCIENCE & TECHNOLOGY,53(15),9102-9108. |
| MLA | Li, Jian,et al."Efficient Removal of Fluoride by Complexation Extraction: Mechanism and Thermodynamics".ENVIRONMENTAL SCIENCE & TECHNOLOGY 53.15(2019):9102-9108. |
入库方式： OAI收割
来源：过程工程研究所
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