A rapid method for the synthesis of perovskite (ATiO(3), A = Ca, Sr, Ba) in molten chloride
文献类型：期刊论文
| 作者 | Wang, Dong1,2; Lu, Jijun1,2; Gou, Jie1,2; Wang, Zhi1,2; Wang, Mingyong3; Gong, Xuzhong1,2; Hao, Shishuo1,2 |
| 刊名 | CERAMICS INTERNATIONAL
 |
| 出版日期 | 2019-10-15 |
| 卷号 | 45期号:15页码:19547-19549 |
| ISSN号 | 0272-8842 |
| 关键词 | Perovskite Molten salt synthesis (MSS) Liquid-solid reaction Phase transformation Cation size Ferroelectrics |
| DOI | 10.1016/j.ceramint.2019.06.113 |
| 英文摘要 | This paper reports the rapid synthesis of perovskite (ATiO(3), A = Ca, Sr, Ba) via molten salt method within 10 min BaCl2 or CaCl2 was used due to their excellent solubility of O2- which enables faster mass transfer transport in the liquid phase. TiO2, ACl(2) and CaO (or BaCO3) were used as the precursors. The obtained ATiO(3) show high chemical and phase purity. Studies found that cation size in ATiO(3) plays an important role in the transformation between different perovskites. The method may provide a generalized methodology for rapid preparation of other important perovskites. |
| WOS关键词 | FORMATION MECHANISM |
| 资助项目 | National Natural Science Foundation of China[51604255] ; National Natural Science Foundation of China[U1702251] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000483454200173 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30736]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Dong; Wang, Zhi |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Univ Sci & Technol Beijing, Met & Ecol Engn Sch, State Key Lab Adv Met, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Dong,Lu, Jijun,Gou, Jie,et al. A rapid method for the synthesis of perovskite (ATiO(3), A = Ca, Sr, Ba) in molten chloride[J]. CERAMICS INTERNATIONAL,2019,45(15):19547-19549. |
| APA | Wang, Dong.,Lu, Jijun.,Gou, Jie.,Wang, Zhi.,Wang, Mingyong.,...&Hao, Shishuo.(2019).A rapid method for the synthesis of perovskite (ATiO(3), A = Ca, Sr, Ba) in molten chloride.CERAMICS INTERNATIONAL,45(15),19547-19549. |
| MLA | Wang, Dong,et al."A rapid method for the synthesis of perovskite (ATiO(3), A = Ca, Sr, Ba) in molten chloride".CERAMICS INTERNATIONAL 45.15(2019):19547-19549. |
入库方式： OAI收割
来源：过程工程研究所
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