Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification
文献类型：期刊论文
| 作者 | Tian, Yun2; Li, Yuchao1,2; Zuo, Cuncun2; Yin, Defeng2; Wang, Ling3; Zheng, Yanxia2; Huang, Haofei2; Fu, Zhongjun2; Wang, Ming2 |
| 刊名 | CHEMNANOMAT
 |
| 出版日期 | 2019-09-27 |
| 页码 | 7 |
| 关键词 | Porous MnCeOx Ionic liquids Nano-Au Methyl methacrylate Oxidative esterification |
| ISSN号 | 2199-692X |
| DOI | 10.1002/cnma.201900408 |
| 英文摘要 | Porous MnCeOx solid solutions nanorods (PN-MnCeOx) with different pore sizes were prepared using different carbon chain lengths ionic liquids (C(10)mimCl, C(12)mimCl and C(14)mimCl). Series of novel catalysts with nano-Au supported on the PN-MnCeOx, were synthesized and applied to oxidative esterification of aldehydes (benzaldehyde derivatives or methacrolein - MAL) to esters. Catalytic performance was evaluated in batch reactor and the relatively optimum catalyst was screened out. Kinds of characterization methods, such as XRD, TEM, XPS and BET, were applied to analyze crystal plane, microstructure, specific surface area, and porous structure of the catalysts and the structure-activity relationship could be reasonably explained. The cyclic stability of the catalyst was also tested more than 7 times using MAL and methanol for methyl methacrylate synthesis via one step oxidative esterification. |
| WOS关键词 | GOLD NANOPARTICLES ; CO OXIDATION ; AEROBIC OXIDATION ; CATALYSTS ; DEACTIVATION ; AU ; METHACROLEIN ; ALDEHYDES ; ALCOHOLS ; OXIDES |
| 资助项目 | Natural Science Foundation of China[21706149] ; Shandong Provincial Natural Science Foundation[ZR2017BB079] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000487833700001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | Natural Science Foundation of China ; Shandong Provincial Natural Science Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30858]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Yuchao |
| 作者单位 | 1.266 Xincun West Rd, Zhangdian Dist 255000, Zibo, Peoples R China 2.Shandong Univ Technol, Sch Chem & Chem Engn, Zibo 255049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Yun,Li, Yuchao,Zuo, Cuncun,et al. Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification[J]. CHEMNANOMAT,2019:7. |
| APA | Tian, Yun.,Li, Yuchao.,Zuo, Cuncun.,Yin, Defeng.,Wang, Ling.,...&Wang, Ming.(2019).Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification.CHEMNANOMAT,7. |
| MLA | Tian, Yun,et al."Ionic-Liquid-Modified Porous Au/CeMnOx Nanorods for Methyl Methacrylate (MMA) Synthesis via Direct Oxidative Esterification".CHEMNANOMAT (2019):7. |
入库方式： OAI收割
来源：过程工程研究所
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