Epoxide ring-opening reaction promoted by ionic liquid reactivity: interplay of experimental and theoretical studies
文献类型：期刊论文
| 作者 | Chen, Shengxin3; Zeng, Guixiang2; Li, Yingwei1,3; He, Bin1,3; Liu, Ruixia1,3; Zhang, Suojiag1,3 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2019-10-21 |
| 卷号 | 9期号:20页码:5567-5571 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c9cy00953a |
| 英文摘要 | Ionic liquids (ILs) have been widely introduced recently into the epoxide ring-opening reaction as catalysts or solvent without considering the chemical stability of ILs in propylene oxide (PO). Through a combination of electrospray-ionization quadrupole time-of-flight mass spectrometry (ESI-QTOF-MS) investigations and quantum-chemical calculations, we demonstrate that AC- (acetate) and MC-(methylcarbonate) based ILs exhibit modified activity for ring opening of PO compared with the reaction between ILs and epoxide compounds. The chemically unstable ILs and the solvent effect can also dominate the catalytic performance of the coupling reaction of PO with methanol. Based on these findings, we further design the reaction process for highly efficient synthesis of propylene glycol methyl ether, in which the yield of the main product increased more than 40% under the same ILs catalysts. The results explained how the chemical instability and substrate affected the PO coupling reaction and further controlled it. |
| WOS关键词 | PROPYLENE-OXIDE ; 1-METHOXY-2-PROPANOL ; STABILITY ; MECHANISM ; CATALYST ; METHANOL ; SOLVENTS |
| 资助项目 | National Nature Science Foundation of China[21878315] ; One Hundred Talent Program of CAS ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000490981500003 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Nature Science Foundation of China ; One Hundred Talent Program of CAS ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/31199]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Ruixia; Zhang, Suojiag |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Nanjing Univ, Kuang Yaming Honors Sch, Nanjing 210023, Jiangsu, Peoples R China 3.Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Shengxin,Zeng, Guixiang,Li, Yingwei,et al. Epoxide ring-opening reaction promoted by ionic liquid reactivity: interplay of experimental and theoretical studies[J]. CATALYSIS SCIENCE & TECHNOLOGY,2019,9(20):5567-5571. |
| APA | Chen, Shengxin,Zeng, Guixiang,Li, Yingwei,He, Bin,Liu, Ruixia,&Zhang, Suojiag.(2019).Epoxide ring-opening reaction promoted by ionic liquid reactivity: interplay of experimental and theoretical studies.CATALYSIS SCIENCE & TECHNOLOGY,9(20),5567-5571. |
| MLA | Chen, Shengxin,et al."Epoxide ring-opening reaction promoted by ionic liquid reactivity: interplay of experimental and theoretical studies".CATALYSIS SCIENCE & TECHNOLOGY 9.20(2019):5567-5571. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。