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Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models

文献类型：期刊论文

作者Zhao, Hui1,4; Li, Jie4; Wang, Lei3,4; Li, Chunshan3,4; Li, Ping2
刊名INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
出版日期2019-10-02
卷号58期号:2页码:18378-18386
ISSN号0888-5885
DOI10.1021/acs.iecr.9b02723
英文摘要The thermodynamics of 1,3,5-trioxane, methyl acrylate, methyl acetate, and water were systematically investigated, in terms of NRTL and UNIQUAC models. Solubility data of 1,3,5-trioxane in methyl acetate and methyl acrylate were reported. Vapor-liquid equilibria (VLE) data of 1,3,5-trioxane + methyl acetate and 1,3,5-trioxane + methyl acrylate binary systems were measured. The liquid-liquid equilibria (LLE) of 1,3,5-trioxane + methyl acrylate + water and 1,3,5-trioxane + methyl acrylate + methyl acetate + water mixtures were investigated. The thermodynamic consistency of VLE and LLE experimental data were tested by using Van Ness point method and Othmer-Tobias method, respectively. Binary interaction parameters for VLE and LLE systems were regressed and compared according to the average absolute deviation (AAD) and average absolute deviation in percentage (AAD%) values. Proper model and parameters were applied in the designed separation process of the quaternary mixture.
WOS关键词VAPOR-LIQUID-EQUILIBRIUM ; PLUS WATER ; ISOPROPYL-ALCOHOL ; ACID PRODUCTION ; ACETIC-ACID ; SEPARATION ; METHANOL ; SYSTEM ; BINARY ; DISTILLATION
资助项目National Natural Science Funds[21878293] ; National Natural Science Funds[21576261] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH022] ; K.C.Wong Education Foundation[GJTD-2018-04]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000489001800036
出版者AMER CHEMICAL SOC
资助机构National Natural Science Funds ; Key Research Program of Frontier Sciences, CAS ; K.C.Wong Education Foundation
源URL[http://ir.ipe.ac.cn/handle/122111/31216]  
专题中国科学院过程工程研究所
通讯作者Li, Chunshan
作者单位1.Univ Chinese Acad Sci, Beijing, Peoples R China
2.Ningxia Univ, Sch Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Peoples R China
3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Zhongke Langfang Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Zhao, Hui,Li, Jie,Wang, Lei,et al. Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(2):18378-18386.
APA Zhao, Hui,Li, Jie,Wang, Lei,Li, Chunshan,&Li, Ping.(2019).Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(2),18378-18386.
MLA Zhao, Hui,et al."Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.2(2019):18378-18386.

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来源：过程工程研究所

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