不同载体负载的cr基催化剂催化co2氧化异丁烷脱氢制异丁烯
文献类型：期刊论文
| 作者 | 孙果宋1; 黄青则2; 李会泉3; 柳海涛3; 张钊3; 王兴瑞3; 王秋萍2; 王金淑1 |
| 刊名 | 催化学报
 |
| 出版日期 | 2011 |
| 卷号 | 32期号:8页码:1424 |
| ISSN号 | 0253-9837 |
| 英文摘要 | The effect of supports (MSU-1,), gamma-Al2O3, AC (activated carbon), and MgO) on the catalytic activity of Cr-based catalysts was investigated for the dehydrogenation of isobutane with CO2. The catalytic activity was in the order of CrO,IMSU-1 > CrOx/Al2O3 > CrOx/AC > CrOx/MgO. The catalysts were characterized by N-2 adsorption-desorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and temperature-programmed desorption (TPD). The XRD results indicate that the active species of Cr are dispersed well on the supports. N-2 adsorption-desorption shows that the support MSU-1 has the largest surface area (804.2 m(2)/g), which results in excellent dispersion of Cr and highest activity. The XPS results reveal that Cr6+ is one of the active centers. The results of NH3-TPD indicate that catalyst activity is proportional to the amount of weak acid adsorption sites. As a result, the best support is the MSU-1 zeolite owing to its high specific area and a large amount of weak acid sites. The 59.2% conversion of isobutane and the 39.5% yield of isobutene are achieved on the CrOx/MSU-1 catalyst. |
| 语种 | 英语 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/32852]  |
| 专题 | 中国科学院过程工程研究所 |
| 作者单位 | 1.北京工业大学 2.广西民族大学 3.中国科学院过程工程研究所 |
| 推荐引用方式 GB/T 7714 | 孙果宋,黄青则,李会泉,等. 不同载体负载的cr基催化剂催化co2氧化异丁烷脱氢制异丁烯[J]. 催化学报,2011,32(8):1424. |
| APA | 孙果宋.,黄青则.,李会泉.,柳海涛.,张钊.,...&王金淑.(2011).不同载体负载的cr基催化剂催化co2氧化异丁烷脱氢制异丁烯.催化学报,32(8),1424. |
| MLA | 孙果宋,et al."不同载体负载的cr基催化剂催化co2氧化异丁烷脱氢制异丁烯".催化学报 32.8(2011):1424. |
入库方式： OAI收割
来源：过程工程研究所
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