Eco-friendly and high-performance photoelectrochemical anode based on AgInS2 quantum dots embedded in 3D graphene nanowalls
文献类型：期刊论文
| 作者 | Nong, Jinpeng1,2; Lan, Guilian2; Jin, Weifeng2; Luo, Peng2; Guo, Caicheng2; Tang, Xiaosheng2; Zang, Zhigang2; Wei, Wei1,2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2019-08-28 |
| 卷号 | 7期号:32页码:9830-9839 |
| ISSN号 | 2050-7526 |
| DOI | 10.1039/c9tc01395d |
| 通讯作者 | Zang, Zhigang(zangzg@cqu.edu.cn) ; Wei, Wei(wwei@cqu.edu.cn) |
| 英文摘要 | Photoelectrochemical (PEC) cells offer a promising approach for developing a solar energy conversion system to resolve the increasingly serious energy crisis and environmental issues. However, the lack of stable and eco-friendly electrodes hampers their practical applications. Herein, we prepare an eco-friendly photoanode with enhanced PEC performance embedding AgInS2 quantum dots (QDs) into three-dimensional (3D) graphene nanowalls (GNWs). AgInS2 QDs with tunable PL emissions are synthesized using a facile hydrothermal method and then deposited on GNWs directly grown on silica by a catalyst-free method. Benefitting from the interconnected 3D conductive network, GNWs act as an outstanding electron acceptor to transport the photogenerated carriers of AgInS2 QDs. The experimental results demonstrate that the AgInS2/GNWs photoanodes exhibit rapid photoresponse upon light excitation with comparable short rise-time (0.23 s) and decay-time (0.41 s). By optimizing the reaction temperature of the QDs, a photo-current density of 145 mu A cm(-2) can be achieved due to the effective separation of the photogenerated carriers. Meanwhile, the as-prepared photoanodes exhibit excellent stability of the photoresponse for more than 4000 s of on-off switching and one-month duration. Our study provides a new strategy to construct an eco-friendly PEC system with high performance which shows potential applications for PEC-type devices. |
| 资助项目 | National Natural Science Foundation of China[61875025] ; National Natural Science Foundation of China[61675037] ; graduate research and innovation foundation of Chongqing, China[CYB17018] ; Chongqing Research Program of Basic Research and Frontier Technology[cstc2017jcyjBX0048] ; Chongqing Research Program of Basic Research and Frontier Technology[cstc2017jcyjBX0054] ; Fundamental Research Funds for the Central Universities[2018CDQYGD0022] ; Fundamental Research Funds for the Central Universities[cqu2018CDHB1B03] |
| WOS研究方向 | Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000481584000036 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/9611]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Zang, Zhigang; Wei, Wei |
| 作者单位 | 1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing Key Lab Multiscale Mfg Technol, Chongqing 400714, Peoples R China 2.Chongqing Univ, Coll Optoelect Engn, Key Lab Optoelect Technol & Syst, Minist Educ China, Chongqing 400044, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nong, Jinpeng,Lan, Guilian,Jin, Weifeng,et al. Eco-friendly and high-performance photoelectrochemical anode based on AgInS2 quantum dots embedded in 3D graphene nanowalls[J]. JOURNAL OF MATERIALS CHEMISTRY C,2019,7(32):9830-9839. |
| APA | Nong, Jinpeng.,Lan, Guilian.,Jin, Weifeng.,Luo, Peng.,Guo, Caicheng.,...&Wei, Wei.(2019).Eco-friendly and high-performance photoelectrochemical anode based on AgInS2 quantum dots embedded in 3D graphene nanowalls.JOURNAL OF MATERIALS CHEMISTRY C,7(32),9830-9839. |
| MLA | Nong, Jinpeng,et al."Eco-friendly and high-performance photoelectrochemical anode based on AgInS2 quantum dots embedded in 3D graphene nanowalls".JOURNAL OF MATERIALS CHEMISTRY C 7.32(2019):9830-9839. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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