Effect of the Inherent Structure of Rh Nanocrystals on the Hydriding Behavior under Pressure
文献类型：期刊论文
| 作者 | Liu, Chuang2; Jiang, Shuqing1; Sui, Yongming2; Chen, Yaping2; Xiao, Guanjun2; Chen, Xiao-Jia1,3; Shu, Haiyun3; Duan, Defang2; Li, Xue2; Liu, Hanyu2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY LETTERS
 |
| 出版日期 | 2019-02-21 |
| 卷号 | 10期号:4页码:774-779 |
| ISSN号 | 1948-7185 |
| DOI | 10.1021/acs.jpclett.9b00216 |
| 通讯作者 | Sui, Yongming(suiym@jlu.edu.cn) ; Zou, Bo(zoubo@jlu.edu.cn) |
| 英文摘要 | Tailoring the inherent structure of materials is an effective way to improve the hydrogen storage capacity of metal materials. In this work, we report the effect of rhodium (Rh) nanocrystals (NCs) on the hydrogenation reaction. We found that Rh NCs could form rhodium monohydride (RhH) at a lower pressure than the bulk Rh because of its high specific surface area and structure defects. In addition, Rh NCs in the form of icosahedrons exhibited a much higher hydrogen absorption efficiency than Rh nanocubes. Furthermore, much smaller irregular Rh nanoparticles are even partially converted to RhH at lower pressure because of the nanosize effect. We thus believe that it is possible to design materials with excellent hydrogen storage properties under mild conditions. |
| WOS关键词 | HYDROGEN STORAGE PROPERTIES ; METAL-HYDRIDES ; NANOPARTICLES ; PROGRESS |
| 资助项目 | National Natural Science Foundation of China[21725304] ; National Natural Science Foundation of China[11774124] ; National Natural Science Foundation of China[11774125] ; National Natural Science Foundation of China[21673100] ; Chang Jiang Scholars Program of China[T2016051] ; Changbai Mountain Scholars Program[2013007] ; Technology Development Program of Jilin Province[20180101285JC] ; National Defense Science and Technology Key Laboratory Fund[6142A0306010917] ; JLU Science and Technology Innovative Research Team[2017TD-01] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000459948800012 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Chang Jiang Scholars Program of China ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Changbai Mountain Scholars Program ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; Technology Development Program of Jilin Province ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; National Defense Science and Technology Key Laboratory Fund ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team ; JLU Science and Technology Innovative Research Team |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/42313]  |
| 专题 | 合肥物质科学研究院_中科院固体物理研究所 |
| 通讯作者 | Sui, Yongming; Zou, Bo |
| 作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230000, Anhui, Peoples R China 2.Jilin Univ, Coll Phys, State Key Lab Superhard Mat, Changchun 130012, Jilin, Peoples R China 3.Ctr High Pressure Sci & Technol Adv Res, Shanghai 211203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Chuang,Jiang, Shuqing,Sui, Yongming,et al. Effect of the Inherent Structure of Rh Nanocrystals on the Hydriding Behavior under Pressure[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2019,10(4):774-779. |
| APA | Liu, Chuang.,Jiang, Shuqing.,Sui, Yongming.,Chen, Yaping.,Xiao, Guanjun.,...&Zou, Bo.(2019).Effect of the Inherent Structure of Rh Nanocrystals on the Hydriding Behavior under Pressure.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,10(4),774-779. |
| MLA | Liu, Chuang,et al."Effect of the Inherent Structure of Rh Nanocrystals on the Hydriding Behavior under Pressure".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 10.4(2019):774-779. |
入库方式： OAI收割
来源：合肥物质科学研究院
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