A copper nanocluster incorporated nanogel: Confinement-assisted emission enhancement for zinc ion detection in living cells
文献类型：期刊论文
| 作者 | Gao, XQ; Zhuang, XM; Tian, CY; Liu, HT; Lai, WF; Wang, ZG; Yang, XM; Chen, LX ; Rogach, AL
|
| 刊名 | SENSORS AND ACTUATORS B-CHEMICAL
 |
| 出版日期 | 2020-03-15 |
| 卷号 | 307页码:127626 |
| 关键词 | Copper nanoclusters Glycol chitosan Aggregation induced emission Zinc(II) detection Cell imaging |
| DOI | 10.1016/j.snb.2019.127626 |
| 产权排序 | [Gao, Xueqing ; Zhuang, Xuming ; Tian, Chunyuan ; Liu, Huitao] Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Peoples R China ; [Zhuang, Xuming ; Yang, Xuming ; Rogach, Andrey L.] City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R China ; [Zhuang, Xuming ; Yang, Xuming ; Rogach, Andrey L.] City Univ Hong Kong, CFP, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R China ; [Lai, Wing-Fu] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China ; [Wang, Zhenguang] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China ; [Chen, Lingxin] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China ; [Rogach, Andrey L.] City Univ Hong Kong, Shenzhen Res Inst, Shenzhen 518057, Peoples R China |
| 文献子类 | Article |
| 英文摘要 | In this work, copper nanoclusters (CuNCs), in which cysteine served as both a reducing agent and a protection ligand, were synthesized, and impregnated into a nanogel of glycol chitosan (GC), forming a CuNCs@GC nanocomposite. The stability of CuNCs incorporated into a nanogel was significantly improved, while their photoluminescence (PL) intensity of CuNCs@GC could be tuned by controlling the pH of the system. The nanocomposite was used as a platform for the "turn on" detection of Zn2+, making use of the effect of aggregation induced emission (AIE) enhancement. By adjusting the pH of the system to 7.4, the PL of CuNCs@GC was turned down so as to minimize the background signal. In the presence of Zn2+, the nanoclusters in CuNCs@GC changed from the dispersed state to the aggregated state, which resulted in an increase of the PL intensity. A linear response between the PL intensity and the concentration of Zn2+, in the range from 1.5 mu M to 750 mu M, was obtained, achieving a detection limit of 1.0 mu M. Furthermore, the CuNCs@GC nanocomposite was found to be applicable to live cell imaging, owing to the high biocompatibility and protective effects of GC. |
| WOS关键词 | AGGREGATION-INDUCED EMISSION ; ATOMIC-ABSORPTION-SPECTROMETRY ; FLUORESCENT NANOSENSOR ; WATER ; FABRICATION ; CLUSTERS ; CADMIUM ; NICKEL ; COBALT ; SENSOR |
| WOS研究方向 | Chemistry, Analytical ; Electrochemistry ; Instruments & Instrumentation |
| 语种 | 英语 |
| WOS记录号 | WOS:000508110400004 |
| 资助机构 | National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21778047, 21804030] ; Hong Kong Scholars Program [XJ2017052] ; Science Technology and Innovation Committee of Shenzhen Municipality [JCYJ20170818104224667] ; Taishan Scholar Project Special Funding [ts20190962] |
| 源URL | [http://ir.yic.ac.cn/handle/133337/24739]  |
| 专题 | 烟台海岸带研究所_山东省海岸带环境工程技术研究中心 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China; 2.Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Peoples R China; 3.City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R China; 4.City Univ Hong Kong, CFP, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R China; 5.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China; 6.Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China; 7.City Univ Hong Kong, Shenzhen Res Inst, Shenzhen 518057, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, XQ,Zhuang, XM,Tian, CY,et al. A copper nanocluster incorporated nanogel: Confinement-assisted emission enhancement for zinc ion detection in living cells[J]. SENSORS AND ACTUATORS B-CHEMICAL,2020,307:127626. |
| APA | Gao, XQ.,Zhuang, XM.,Tian, CY.,Liu, HT.,Lai, WF.,...&Rogach, AL.(2020).A copper nanocluster incorporated nanogel: Confinement-assisted emission enhancement for zinc ion detection in living cells.SENSORS AND ACTUATORS B-CHEMICAL,307,127626. |
| MLA | Gao, XQ,et al."A copper nanocluster incorporated nanogel: Confinement-assisted emission enhancement for zinc ion detection in living cells".SENSORS AND ACTUATORS B-CHEMICAL 307(2020):127626. |
入库方式： OAI收割
来源：烟台海岸带研究所
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