中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effects of macro metals on alkaline phosphatase activity under conditions of sulfide accumulation

文献类型:期刊论文

作者Zhao, GQ; Sheng, YQ; Li, CY; Liu, QQ
刊名SCIENCE OF THE TOTAL ENVIRONMENT
出版日期2019-12-20
卷号697页码:UNSP 134151
关键词Alkaline phosphatase Macro metal Sulfate reduction Organic phosphorus
ISSN号0048-9697
DOI10.1016/j.scitotenv.2019.134151
产权排序[Zhao, Guoqiang ; Sheng, Yanqing ; Li, Changyu ; Liu, Qunqun] Chinese Acad Sci, Res Ctr Coastal Environm Engn Technol Shandong Pr, Yantai Inst Coastal Zone Res, Yantai, Peoples R China ; [Zhao, Guoqiang ; Li, Changyu ; Liu, Qunqun] Univ Chinese Acad Sci, Beijing, Peoples R China
文献子类Article
英文摘要Alkaline phosphatase (AP) is commonly found in aquatic ecosystems as an extracellular enzyme closely related to the biogeochemical cycling of phosphorus. Although the AP activity (APA) is conventionally thought to be a main response to PO43- starvation, significant effects of macro metal elements (Al, Fe, and Ca) and S on the APA were found in this study. The APAwas reduced by Al primarily through the adsorption of the enzyme onto AlOOH colloids. Fe2+ inhibited the APA via a mechanism involving free radical oxidation. The main mechanism by which Ca2+ inhibited the APA was by competing with Mg2+ and Zn2+ for the active sites of the enzyme. Excessive S2- could reduce the APA by removing Zn2+ from the active sites of the enzyme. The inhibition of APA could be reversed if some metal ions (e.g., Fe2+) were precipitated by S2- under reducing conditions. Therefore, in anaerobic ecosystems, the effects of macrometals on APA under conditions of sulfide accumulation may have innovative implications for phosphorus management. (C) 2019 Elsevier B.V. All rights reserved.
WOS关键词BIOGENIC PHOSPHORUS-COMPOUNDS ; ORGANIC PHOSPHORUS ; FRESH-WATER ; STRUCTURAL EVIDENCE ; EUTROPHIC LAKE ; SEDIMENTS ; INHIBITION ; SOIL ; FRACTIONATION ; KINETICS
WOS研究方向Environmental Sciences
语种英语
WOS记录号WOS:000499668600032
资助机构Strategic Priority Research Program of the Chinese Academy of SciencesChinese Academy of Sciences [XDA23050203] ; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [41373100] ; Key Project of Research and Development Plan of Yantai [2018ZHGY083] ; Key Research and Development Program of Shandong Province [2019GSF109002]
源URL[http://ir.yic.ac.cn/handle/133337/24787]  
专题烟台海岸带研究所_山东省海岸带环境工程技术研究中心
烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位1.Univ Chinese Acad Sci, Beijing, Peoples R China
2.Chinese Acad Sci, Res Ctr Coastal Environm Engn Technol Shandong Pr, Yantai Inst Coastal Zone Res, Yantai, Peoples R China;
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GB/T 7714
Zhao, GQ,Sheng, YQ,Li, CY,et al. Effects of macro metals on alkaline phosphatase activity under conditions of sulfide accumulation[J]. SCIENCE OF THE TOTAL ENVIRONMENT,2019,697:UNSP 134151.
APA Zhao, GQ,Sheng, YQ,Li, CY,&Liu, QQ.(2019).Effects of macro metals on alkaline phosphatase activity under conditions of sulfide accumulation.SCIENCE OF THE TOTAL ENVIRONMENT,697,UNSP 134151.
MLA Zhao, GQ,et al."Effects of macro metals on alkaline phosphatase activity under conditions of sulfide accumulation".SCIENCE OF THE TOTAL ENVIRONMENT 697(2019):UNSP 134151.

入库方式: OAI收割

来源:烟台海岸带研究所

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