In-situ fabrication of reduced graphene oxide/leucomethylene blue/platinum nanoparticles modified electrode for voltammetric determination of trace Fe(II) in seawater
文献类型：期刊论文
| 作者 | Ma, S; Pan, DW ; Wei, H; Wang, N; Pan, F; Kang, Q
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| 刊名 | MICROCHEMICAL JOURNAL
 |
| 出版日期 | 2019-12 |
| 卷号 | 151页码:104210 |
| 关键词 | In-situ fabrication Fe(II) Seawater Reduced graphene oxide Leucomethylene blue |
| ISSN号 | 0026-265X |
| DOI | 10.1016/j.microc.2019.104210 |
| 产权排序 | [Ma, Su ; Wei, Hong ; Kang, Qi] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Shandong Prov Key Lab Clean Prod Fine Chem, Minist Educ,Key Lab Mol & Nano Probes, Jinan 250014, Shandong, Peoples R China ; [Pan, Dawei ; Wang, Ning ; Pan, Fei] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China ; [Pan, Dawei ; Pan, Fei] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 文献子类 | Article |
| 英文摘要 | In this work, the modified electrode based on composites of reduced graphene oxide/leucomethylene blue/platinum nanoparticles (rGO/LMB/PtNPs) was fabricated in-situ via an electron relay effect. Cationic dye of methylene blue (MB) was absorbed on the surface of graphene oxide (GO) with through pi-pi bond interactions. Then PtCl62- ions were self-assembled on the surface of the composites of GO/MB through Coulomb interactions. Using NaBH4 as the reducing agent, PtNPs were formed and GO was reduced to rGO. With the aid of PtNPs, MB was catalytically degraded to LMB and a rGO/LMB/PtNPs modified electrode was successfully prepared in situ. Due to the excellent electrochemical properties of rGO and the well-established assistant reductant of MB, as well as the catalytic amplifying effect of PtNPs, this as prepared rGO/LMB/PtNPs modified electrode showed excellent properties for the voltammetric determination of Fe(II) with the linear range of 0.01 to 2 mu m and a detection limit of 3 nM. This modified electrode was successfully applied to detect the content of Fe(II) in seawater. |
| WOS关键词 | CARBON-PASTE ELECTRODE ; METHYLENE-BLUE ; SELECTIVE DETECTION ; GLASSY-CARBON ; ELECTROCHEMICAL DETERMINATION ; GOLD NANOPARTICLES ; DISSOLVED IRON ; REDUCTION ; OXIDE ; PERFORMANCE |
| WOS研究方向 | Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000497250700005 |
| 资助机构 | National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21874083] ; National Natural Science FoundationNational Natural Science Foundation of China [ZR2018MB029] ; Key Research and Development Plan of Shandong Province [2017GHY215002] ; Key Research and Development Plan of Yantai City [2017ZH096] |
| 源URL | [http://ir.yic.ac.cn/handle/133337/24808]  |
| 专题 | 烟台海岸带研究所_山东省海岸带环境工程技术研究中心 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China; 3.Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Shandong Prov Key Lab Clean Prod Fine Chem, Minist Educ,Key Lab Mol & Nano Probes, Jinan 250014, Shandong, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Ma, S,Pan, DW,Wei, H,et al. In-situ fabrication of reduced graphene oxide/leucomethylene blue/platinum nanoparticles modified electrode for voltammetric determination of trace Fe(II) in seawater[J]. MICROCHEMICAL JOURNAL,2019,151:104210. |
| APA | Ma, S,Pan, DW,Wei, H,Wang, N,Pan, F,&Kang, Q.(2019).In-situ fabrication of reduced graphene oxide/leucomethylene blue/platinum nanoparticles modified electrode for voltammetric determination of trace Fe(II) in seawater.MICROCHEMICAL JOURNAL,151,104210. |
| MLA | Ma, S,et al."In-situ fabrication of reduced graphene oxide/leucomethylene blue/platinum nanoparticles modified electrode for voltammetric determination of trace Fe(II) in seawater".MICROCHEMICAL JOURNAL 151(2019):104210. |
入库方式： OAI收割
来源：烟台海岸带研究所
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