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Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone

文献类型：期刊论文

作者Long, Yang1,2,3; Ding, Yiming2,3,4; Wu, Hai2,3,4; Qu, Chunlei2,3,4; Liang, Hong2,3,4; Zhang, Min2,3,4; Zhao, Xiaoli2,3,4; Long, Xianwen2,3,4; Wang, Shu1; Puno, Pema-Tenzin2,3
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2019-11-08
页码6
关键词5+2 cycloaddition dimerization natural products perezoperezone total synthesis
ISSN号1433-7851
DOI10.1002/anie.201911978
通讯作者Deng, Jun(dengjun@mail.kib.ac.cn)
英文摘要The first copper-catalyzed intermolecular [5+2] homodimerization of hydroxy p-quinone is presented, furnishing bicyclo[3.2.1]octadienone core structures in typically good yields and excellent diastereoselectivities. Applying this synthetic approach enables a concise nine-step total synthesis of (-)-perezoperezone from commercially available 3,5-dimethoxytoluene.
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000495083600001
源URL[http://ir.kib.ac.cn/handle/151853/70979]  
专题昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
通讯作者Deng, Jun
作者单位1.Sichuan Univ, West China Sch Pharm, Dept Med Nat Prod, Chengdu 610041, Sichuan, Peoples R China
2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, 132 Lanhei Rd, Kunming, Yunnan, Peoples R China
3.Chinese Acad Sci, Kunming Inst Bot, Yunnan Key Lab Nat Med Chem, 132 Lanhei Rd, Kunming, Yunnan, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Long, Yang,Ding, Yiming,Wu, Hai,et al. Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019:6.
APA Long, Yang.,Ding, Yiming.,Wu, Hai.,Qu, Chunlei.,Liang, Hong.,...&Deng, Jun.(2019).Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,6.
MLA Long, Yang,et al."Total Synthesis of (-)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019):6.

入库方式： OAI收割

来源：昆明植物研究所

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