Synthesis and nonlinear optical properties of novel conjugated small molecules based on coumarin donor
文献类型：期刊论文
| 作者 | Li, Yuefeng1,5; Yang, Zhimao3,4; Hao, Baoqiang2; Wang, Shujuan1; Ouyang, Canbin2; Cao, Aocheng2 |
| 刊名 | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
 |
| 出版日期 | 2019-10-23 |
| 页码 | 7 |
| ISSN号 | 0957-4522 |
| DOI | 10.1007/s10854-019-02364-z |
| 英文摘要 | Novel electronic donor with polycyclic structure based on coumarin was designed and prepared. Pyrrolidine acting as an isolated group was introduced to the donor by the Buchwald-Hartwig amination reaction. Such a novel electronic donor demonstrated great electron-donating capability and an excellent isolation effect. Both chromophores exhibited a D-pi-A-pi-A molecular structure. Such a structure has great advantages in energy matching, dipole interaction, and electron transfer, compared to the single D-pi-A structure. The chemical structures of novel chromophores based on this donor were characterized by H-1 nuclear magnetic resonance spectroscopy, C-13 nuclear magnetic resonance spectroscopy, and mass spectrometry. The largest electro-optic coefficients are approximately 31.2 and 42.6 pm/V for chromophores NLO-C and NLO-P, respectively, at 1310 nm; otherwise, both chromophores NLO-C and NLO-P exhibit high thermal decomposition temperatures, i.e., 276 and 237 degrees C, respectively. |
| 资助项目 | National Key Research and Development Program of China[2016YFD0200208] ; National Key Research and Development Program of China[2017YFD0201608] ; National Key Research and Development Program of China[2016YFC1201203] |
| WOS研究方向 | Engineering ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000492021600004 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.amss.ac.cn/handle/2S8OKBNM/50714]  |
| 专题 | 中国科学院数学与系统科学研究院 |
| 通讯作者 | Wang, Shujuan; Ouyang, Canbin; Cao, Aocheng |
| 作者单位 | 1.Xi An Jiao Tong Univ, Sch Sci, Dept Appl Chem, Xian 710049, Shaanxi, Peoples R China 2.Chinese Acad Agr Sci, Inst Plant Protect, Key Lab Integrated Pest Management Crops, Minist Agr, Beijing 100193, Peoples R China 3.Chinese Acad Sci, Acad Math & Syst Sci, Beijing 100190, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100043, Peoples R China 5.Xian KaiLi Catalyst & New Mat Co Ltd, Xian 710201, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yuefeng,Yang, Zhimao,Hao, Baoqiang,et al. Synthesis and nonlinear optical properties of novel conjugated small molecules based on coumarin donor[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,2019:7. |
| APA | Li, Yuefeng,Yang, Zhimao,Hao, Baoqiang,Wang, Shujuan,Ouyang, Canbin,&Cao, Aocheng.(2019).Synthesis and nonlinear optical properties of novel conjugated small molecules based on coumarin donor.JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,7. |
| MLA | Li, Yuefeng,et al."Synthesis and nonlinear optical properties of novel conjugated small molecules based on coumarin donor".JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2019):7. |
入库方式： OAI收割
来源：数学与系统科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。