中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 上海药物研究所
  3. 中国科学院上海药物研究所
Direct C(sp(3))-H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI

文献类型：期刊论文

作者Zhao, Yong-Long1,4,5; Tang, Yong-Qin1,4,5; Fei, Xing-Hai1,4,5; Yang, Fen-Fen1,4,5; Cao, Zhuo-Xian1,4,5; Duan, Dong-Zhu3; Zhao, Qing-Jie2; Yang, Yuan-Yong1,4,5; Zhou, Meng1,4,5; He, Bin1,4,5
刊名GREEN CHEMISTRY
出版日期2020-04-21
卷号22期号:8页码:2354-2358
ISSN号1463-9262
DOI10.1039/c9gc04446a
通讯作者Zhao, Yong-Long(zhaoyl05@126.com)
英文摘要The first KI-catalyzed direct acyloxylation of indolin-3-ones with carboxylic acids has been developed using 30% aq. H2O2 as a green oxidant at room temperature. Through this strategy, various C2-acyloxy indolin-3-ones were obtained in up to 96% yield. Moreover, the C2-acyloxy indolin-3-ones can serve as versatile intermediates for the synthesis of nucleophilic 2-monoarylated indolin-3-ones and 3-ylidene indoles.
WOS关键词ASYMMETRIC MICHAEL ADDITION ; C-H FUNCTIONALIZATION ; 2-SUBSTITUTED INDOLIN-3-ONES ; OXIDATION ; 1-ACETYLINDOLIN-3-ONES ; QUATERNARY ; ALKALOIDS ; INDOLES ; ACCESS
资助项目National Natural Science Foundation of China[21502030] ; National Natural Science Foundation of China[21662010] ; National Natural Science Foundation of China[81960628] ; National Natural Science Foundation of China[U1812403] ; State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University[FAMP201904K] ; Science and Technology Department of Guizhou Province[QKHRCPT[2017] 5101] ; Guizhou Medical University 2018 Academic New Seedling Training and Innovation Exploration Project[[2018] 5779-68] ; One Hundred Talents Program of Guizhou Province (2015) ; Shaanxi Provincial Key Laboratory Project[16JS009] ; Baoji University of Arts And Sciences[ZK16052]
WOS研究方向Chemistry ; Science & Technology - Other Topics
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000530725600002
源URL[http://119.78.100.183/handle/2S10ELR8/280237]  
专题中国科学院上海药物研究所
通讯作者Zhao, Yong-Long
作者单位1.Guizhou Med Univ, TCM, Minist Educ, Guiyang 550004, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
3.Baoji Univ Arts & Sci, Shaanxi Key Lab Phytochem, Baoji 721013, Peoples R China
4.Guizhou Med Univ, Engn Res Ctr Dev & Applicat Ethn Med, State Key Lab Funct & Applicat Med Plants, Guiyang 550004, Peoples R China
5.Guizhou Med Univ, Sch Pharm, Guiyang 550004, Peoples R China
推荐引用方式
GB/T 7714		 Zhao, Yong-Long,Tang, Yong-Qin,Fei, Xing-Hai,et al. Direct C(sp(3))-H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI[J]. GREEN CHEMISTRY,2020,22(8):2354-2358.
APA Zhao, Yong-Long.,Tang, Yong-Qin.,Fei, Xing-Hai.,Yang, Fen-Fen.,Cao, Zhuo-Xian.,...&He, Bin.(2020).Direct C(sp(3))-H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI.GREEN CHEMISTRY,22(8),2354-2358.
MLA Zhao, Yong-Long,et al."Direct C(sp(3))-H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI".GREEN CHEMISTRY 22.8(2020):2354-2358.

入库方式： OAI收割

来源：上海药物研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。