Rh(III)-Catalyzed C-H Bond Activation for the Construction of Heterocycles with sp(3)-Carbon Centers
文献类型:期刊论文
作者 | Wang, Run1,2; Xie, Xiong1,2; Liu, Hong1,2![]() ![]() |
刊名 | CATALYSTS
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出版日期 | 2019-10-01 |
卷号 | 9期号:10页码:29 |
关键词 | C-H bond activation Rhodium(III)-based catalysts heterocycle with sp(3) carbon centers chirality |
DOI | 10.3390/catal9100823 |
通讯作者 | Zhou, Yu(zhouyu@simm.ac.cn) |
英文摘要 | Rh(III)-catalyzed C-H activation features mild reaction conditions, good functional group tolerance, high reaction efficiency, and regioselectivity. Recently, it has attracted tremendous attention and has been employed to synthesize various heterocycles, such as indoles, isoquinolines, isoquinolones, pyrroles, pyridines, and polyheterocycles, which are important privileged structures in biological molecules, natural products, and agrochemicals. In this short review, we attempt to present an overview of recent advances in Rh(III)-mediated C-H bond activation to generate diverse heterocyclic scaffolds with sp(3) carbon centers. |
WOS关键词 | RH-CATALYZED ANNULATIONS ; DIELS-ALDER REACTIONS ; N-SULFONYL KETIMINES ; FORM GAMMA-LACTAMS ; INTERNAL ALKYNES ; DIAZO-COMPOUNDS ; NITROGEN-HETEROCYCLES ; SPIROCYCLIC SULTAM ; CYCLIZATION ; FUNCTIONALIZATION |
资助项目 | National Natural Science Foundation of China[21672232] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA12040217] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA12020375] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000498266100039 |
出版者 | MDPI |
源URL | [http://119.78.100.183/handle/2S10ELR8/282080] ![]() |
专题 | 新药研究国家重点实验室 |
通讯作者 | Zhou, Yu |
作者单位 | 1.Univ Chinese Acad Sci, Sch Pharm, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Run,Xie, Xiong,Liu, Hong,et al. Rh(III)-Catalyzed C-H Bond Activation for the Construction of Heterocycles with sp(3)-Carbon Centers[J]. CATALYSTS,2019,9(10):29. |
APA | Wang, Run,Xie, Xiong,Liu, Hong,&Zhou, Yu.(2019).Rh(III)-Catalyzed C-H Bond Activation for the Construction of Heterocycles with sp(3)-Carbon Centers.CATALYSTS,9(10),29. |
MLA | Wang, Run,et al."Rh(III)-Catalyzed C-H Bond Activation for the Construction of Heterocycles with sp(3)-Carbon Centers".CATALYSTS 9.10(2019):29. |
入库方式: OAI收割
来源:上海药物研究所
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