金属催化的碳杂键对炔键的加成反应研究进展
文献类型：期刊论文
| 作者 | 赵飞1; 贾秀稳1; 王东萍1; 费朝丽1; 吴成林2; 王江2 ; 柳红2
|
| 刊名 | 有机化学
 |
| 出版日期 | 2017 |
| 卷号 | 37期号:2页码:284 |
| 关键词 | C-N BOND INTRAMOLECULAR TRANS-VINYLSILYLATION TERMINAL ALKYNES UNACTIVATED ALKYNES ACID-CHLORIDES REGIOSELECTIVE CYANOTHIOLATION 2,3-DISUBSTITUTED BENZOFURANS CYCLOISOMERIZATION REACTION STEREOSELECTIVE-SYNTHESIS CONVENIENT SYNTHESIS metal-catalyzed carbon-hetero bonds alkynes addition reactions |
| ISSN号 | 0253-2786 |
| DOI | 10.6023/cjoc201607035 |
| 英文摘要 | The addition of carbon-hetero bonds to alkynes has become an important apporach for the functionalization of carbon-carbon triple bonds. It can construct two bonds, namely one carbon-carbon bond and one carbon-hetero bond, in a single one step. These addition reactions feature high efficiency and high atom-economy. In recent years, metal-catalyzed (Al, Fe, Ni, Cu, Ga, Ru, Rh, Pd, Hf, Ir, Pt, Au, Bi, etc.) addition of many various kinds of carbon-hetero bonds to alkynes has achieved lots of important developments. According to the types of carbon-hetero bonds, the addition of 8 different kinds of carbon-hetero bonds C-H, C-B, C-N, C-O, C-Si, C-S, C-X (X=Cl, Br, I), C-Se to alkynes is reviewed in this paper, and the reaction conditions, reaction selectivities (regioselectivities and stereoselectivities) and reaction mechanisms are also discussed and summarized. |
| 资助项目 | [National Natural Science Foundation of China] ; [Open Project Program of Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province] |
| 语种 | 英语 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/286702]  |
| 专题 | 中国科学院上海药物研究所 |
| 作者单位 | 1.成都学院 2.中国科学院上海药物研究所 |
| 推荐引用方式 GB/T 7714 | 赵飞,贾秀稳,王东萍,等. 金属催化的碳杂键对炔键的加成反应研究进展[J]. 有机化学,2017,37(2):284. |
| APA | 赵飞.,贾秀稳.,王东萍.,费朝丽.,吴成林.,...&柳红.(2017).金属催化的碳杂键对炔键的加成反应研究进展.有机化学,37(2),284. |
| MLA | 赵飞,et al."金属催化的碳杂键对炔键的加成反应研究进展".有机化学 37.2(2017):284. |
入库方式： OAI收割
来源：上海药物研究所
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