chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters
文献类型：期刊论文
| 作者 | Zhu Tingshun; Xu Minghua
|
| 刊名 | chinesejournalofchemistry
 |
| 出版日期 | 2013 |
| 卷号 | 31期号:3页码:321 |
| 关键词 | ARYL BORONIC ACIDS ALPHA-KETOESTERS ALPHA,BETA-UNSATURATED KETONES ENANTIOSELECTIVE 1,2-ADDITION ADDITION-REACTIONS HYDROXYLATION ALDEHYDES PALLADACYCLES 1,2-DIKETONES 1,4-ADDITION asymmetric catalysis rhodium sulfur-olefin ligand 1 2-addition stereoselectivity reversal |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201300063 |
| 英文摘要 | Simple and readily available chiral N-(sulfinyl)allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic -ketoesters. By employing the linear or branched sulfinamide-olefin ligands, interesting enantioselectivity as well as regioselectivity reversal in the related asymmetric additions were observed. |
| 资助项目 | [National Natural Science Foundation of China] |
| 语种 | 英语 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/288362]  |
| 专题 | 中国科学院上海药物研究所 |
| 作者单位 | 中国科学院上海药物研究所 |
| 推荐引用方式 GB/T 7714 | Zhu Tingshun,Xu Minghua. chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters[J]. chinesejournalofchemistry,2013,31(3):321. |
| APA | Zhu Tingshun,&Xu Minghua.(2013).chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters.chinesejournalofchemistry,31(3),321. |
| MLA | Zhu Tingshun,et al."chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters".chinesejournalofchemistry 31.3(2013):321. |
入库方式： OAI收割
来源：上海药物研究所
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