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Transition-Metal-Free Aryl-Heteroatom Bond Formation via C-S Bond Cleavage

文献类型：期刊论文

作者Zhao, Jian-Nan2,3; Kayumov, Muzaffar1,2; Wang, Dong-Yu1,2; Zhang, Ao1,2,3
刊名ORGANIC LETTERS
出版日期2019-09-20
卷号21期号:18页码:7303-7306
ISSN号1523-7060
DOI10.1021/acs.orglett.9b02584
通讯作者Wang, Dong-Yu(dongyu.wang@simm.ac.cn) ; Zhang, Ao(aozhang@simm.ac.cn)
英文摘要Aryl-heteroatom bonds (C-Het) are almost ubiquitously present in chemical molecules. However, methods for diverse C-Het bond formations from a simple substrate are limited. Herein, we report a convenient and efficient C-S bond transformation of aryl sulfoniums to various C-Het bonds (C-O, C-S, C-Sn, C-Si, C-Se) in the absence of any transition-metal catalyst. These reactions proceeded in mild conditions with a wide substrate scope.
WOS关键词CATALYZED SILYLATION ; ARYLSULFONIUM SALTS ; COUPLING REACTIONS ; PALLADIUM ; MILD ; FUNCTIONALIZATION ; STANNYLATION ; CONSTRUCTION ; CHEMISTRY ; ARYLATION
资助项目Chinese NSF[21702216] ; Chinese NSF[81773565] ; NST Major Project Key New Drug Creation and Manufacturing Program China[2018ZX09711002-006-003] ; China Postdoctoral Science Foundation[2018T110416] ; China Postdoctoral Science Foundation[2017M621566] ; Sanofi-SIBS 2017 Postdoctoral Fellowship
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000487577200024
出版者AMER CHEMICAL SOC
源URL[http://119.78.100.183/handle/2S10ELR8/288583]  
专题中国科学院上海药物研究所
通讯作者Wang, Dong-Yu; Zhang, Ao
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.SIMM, CAS Key Lab Receptor Res, Shanghai 201203, Peoples R China
3.ShanghaiTech Univ, Sch Life Sci & Technol, Shanghai 201210, Peoples R China
推荐引用方式
GB/T 7714		 Zhao, Jian-Nan,Kayumov, Muzaffar,Wang, Dong-Yu,et al. Transition-Metal-Free Aryl-Heteroatom Bond Formation via C-S Bond Cleavage[J]. ORGANIC LETTERS,2019,21(18):7303-7306.
APA Zhao, Jian-Nan,Kayumov, Muzaffar,Wang, Dong-Yu,&Zhang, Ao.(2019).Transition-Metal-Free Aryl-Heteroatom Bond Formation via C-S Bond Cleavage.ORGANIC LETTERS,21(18),7303-7306.
MLA Zhao, Jian-Nan,et al."Transition-Metal-Free Aryl-Heteroatom Bond Formation via C-S Bond Cleavage".ORGANIC LETTERS 21.18(2019):7303-7306.

入库方式： OAI收割

来源：上海药物研究所

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