Copper-mediated O-arylation of lactols with aryl boronic acids
文献类型：期刊论文
| 作者 | Sui, Jing-Jing1,2; Xiong, De-Cai1,3; Ye, Xin-Shan1,2 |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2019-08-01 |
| 卷号 | 30期号:8页码:1533-1537 |
| 关键词 | Phenolic glycoside O-Arylation Lactol Aryl boronic acid |
| ISSN号 | 1001-8417 |
| DOI | 10.1016/j.cclet.2019.06.014 |
| 通讯作者 | Xiong, De-Cai(decai@bjmu.edu.cn) ; Ye, Xin-Shan(xinshan@bjmu.edu.cn) |
| 英文摘要 | An efficient and novel methodology to access phenolic glycosides has been established by using copper-mediated coupling reaction of aryl boronic acids with hemiacetals. The reaction takes place normally in the presence of Cu(OAc)(2) (1.0 equiv.) and pyridine (2.0 equiv.) at 40 degrees C. This protocol distinguishes itself by wide substrate scope, operational simplicity and giving rise to a myriad of phenolic glycosides in good to excellent yields. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | FACILE SYNTHESIS ; GLYCOSYLATION ; DERIVATIVES ; MITHRAMYCIN ; GLYCALS |
| 资助项目 | National Key R&D Program of China[2018YFA0507602] ; National Natural Science Foundation of China[21572012] ; National Natural Science Foundation of China[21772006] ; State Key Laboratory of Drug Research[SIMM1803KF-02] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000482249800016 |
| 出版者 | ELSEVIER SCIENCE INC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/288733]  |
| 专题 | 新药研究国家重点实验室 |
| 通讯作者 | Xiong, De-Cai; Ye, Xin-Shan |
| 作者单位 | 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China 2.Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sui, Jing-Jing,Xiong, De-Cai,Ye, Xin-Shan. Copper-mediated O-arylation of lactols with aryl boronic acids[J]. CHINESE CHEMICAL LETTERS,2019,30(8):1533-1537. |
| APA | Sui, Jing-Jing,Xiong, De-Cai,&Ye, Xin-Shan.(2019).Copper-mediated O-arylation of lactols with aryl boronic acids.CHINESE CHEMICAL LETTERS,30(8),1533-1537. |
| MLA | Sui, Jing-Jing,et al."Copper-mediated O-arylation of lactols with aryl boronic acids".CHINESE CHEMICAL LETTERS 30.8(2019):1533-1537. |
入库方式： OAI收割
来源：上海药物研究所
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