Palladium-catalyzed carbonylative Sonogashira cross-coupling for the synthesis of alkynones with formic acid as the CO source
文献类型：期刊论文
| 作者 | Lyu, Xue1,2; Sun, Guanglong1,2; Zhou, Yang1,2; Wang, Yingying1,2; Lei, Min1,2 ; Wu, Wanying1,2; Guo, Dean1,2
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| 刊名 | MONATSHEFTE FUR CHEMIE
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| 出版日期 | 2019-02-01 |
| 卷号 | 150期号:2页码:309-315 |
| 关键词 | Sonogashira cross-coupling Aryl iodide Alkyne Palladium Alkynones |
| ISSN号 | 0026-9247 |
| DOI | 10.1007/s00706-018-2331-7 |
| 通讯作者 | Lei, Min(mlei@simm.ac.cn) ; Wu, Wanying(wanyingwu@simm.ac.cn) |
| 英文摘要 | A practical and efficient palladium-catalyzed carbonylative Sonogashira cross-coupling reaction for the synthesis of alkynones from aryl iodides, alkynes, and formic acid as the CO source has been described. Under the assistance of PPh3/I-2, formic acid can be used as the CO source for synthesis of alkynones in moderate-good yields. Furthermore, it is also successfully applied for the modification of natural products, such as vindoline and tabersonin, to obtain the corresponding products. [GRAPHICS] . |
| WOS关键词 | ARYL HALIDES ; 3-COMPONENT SYNTHESIS ; EFFICIENT SYNTHESIS ; TERMINAL ALKYNES ; CONVENIENT ; IODIDES ; AMINOCARBONYLATION ; HYDROXYCARBONYLATION ; CYCLOISOMERIZATION ; ACETYLENES |
| 资助项目 | Special Fund for Strategic Pilot Technology Chinese Academy of Sciences[XDA12040303] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000457316200016 |
| 出版者 | SPRINGER WIEN |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/290636]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Lei, Min; Wu, Wanying |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, Natl Engn Lab TCM Standardizat Technol, Shanghai Res Ctr Modernizat Tradit Chinese Med, Shanghai 201203, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lyu, Xue,Sun, Guanglong,Zhou, Yang,et al. Palladium-catalyzed carbonylative Sonogashira cross-coupling for the synthesis of alkynones with formic acid as the CO source[J]. MONATSHEFTE FUR CHEMIE,2019,150(2):309-315. |
| APA | Lyu, Xue.,Sun, Guanglong.,Zhou, Yang.,Wang, Yingying.,Lei, Min.,...&Guo, Dean.(2019).Palladium-catalyzed carbonylative Sonogashira cross-coupling for the synthesis of alkynones with formic acid as the CO source.MONATSHEFTE FUR CHEMIE,150(2),309-315. |
| MLA | Lyu, Xue,et al."Palladium-catalyzed carbonylative Sonogashira cross-coupling for the synthesis of alkynones with formic acid as the CO source".MONATSHEFTE FUR CHEMIE 150.2(2019):309-315. |
入库方式： OAI收割
来源：上海药物研究所
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