Phase Equilibrium Measurements of the Methacrolein-Methacrylic Acid-Water Ternary System at 101.3 kPa
文献类型:期刊论文
作者 | Li, Jie1,3; Zhao, Hui2,3; Wang, Lei3; Peng, Zhijian1; Li, Chunshan2,3 |
刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
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出版日期 | 2019-12-01 |
卷号 | 64期号:12页码:5523-5528 |
ISSN号 | 0021-9568 |
DOI | 10.1021/acs.jced.9b00649 |
英文摘要 | In this work, the isothermal liquid-liquid equilibrium (LLE) and isobaric vapor-liquid equilibrium (VLE) of the methacrolein-methacrylic acid-water ternary mixture were systematically measured using an LLE cell and improved Rose-Williams still under atmospheric pressure. The thermodynamic consistency of LLE data and VLE data was tested by the Othmer-Tobias and Van Ness methods, respectively. The NRTL, UNIQUAC, and Wilson activity coefficient models have been conducted to correlate binary parameters in prediction phase equilibrium based on experimental data. The reliability of three models in equilibrium calculations has been analyzed in detail. All three models are in good agreement with the experimental data. |
WOS关键词 | VAPOR-LIQUID-EQUILIBRIUM ; SELECTIVE OXIDATION ; ISOBUTANE ; ETHANOL ; THERMODYNAMICS ; PRECURSORS ; EXPRESSION ; ENERGY |
资助项目 | National Natural Science Funds[21878293] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH022] ; NSFC-NRCT Joint Project[51661145012] |
WOS研究方向 | Thermodynamics ; Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000503115000054 |
出版者 | AMER CHEMICAL SOC |
资助机构 | National Natural Science Funds ; Key Research Program of Frontier Sciences, CAS ; NSFC-NRCT Joint Project |
源URL | [http://ir.ipe.ac.cn/handle/122111/38524] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Peng, Zhijian; Li, Chunshan |
作者单位 | 1.China Univ Geosci, Sch Engn & Technol, 29 Xueyuan Rd, Beijing 100083, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jie,Zhao, Hui,Wang, Lei,et al. Phase Equilibrium Measurements of the Methacrolein-Methacrylic Acid-Water Ternary System at 101.3 kPa[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2019,64(12):5523-5528. |
APA | Li, Jie,Zhao, Hui,Wang, Lei,Peng, Zhijian,&Li, Chunshan.(2019).Phase Equilibrium Measurements of the Methacrolein-Methacrylic Acid-Water Ternary System at 101.3 kPa.JOURNAL OF CHEMICAL AND ENGINEERING DATA,64(12),5523-5528. |
MLA | Li, Jie,et al."Phase Equilibrium Measurements of the Methacrolein-Methacrylic Acid-Water Ternary System at 101.3 kPa".JOURNAL OF CHEMICAL AND ENGINEERING DATA 64.12(2019):5523-5528. |
入库方式: OAI收割
来源:过程工程研究所
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