Sustainable Valuable Metal Recovery from the V-Cr-Fe Ternary Slime via Leaching-Selective Complexation
文献类型：期刊论文
| 作者 | Zhang, Yang; Peng, Xuefeng; Fan, Bingqiang; Zang, Nan; Zheng, Shili; Zhang, Yi; Jin, Wei |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2020-01-20 |
| 卷号 | 8期号:2页码:958-965 |
| 关键词 | slime valuable metals ternary complexation selective recovery |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.9b05563 |
| 英文摘要 | The V-Cr-Fe ternary slime is an emerging heavy metal waste after a series of pyro- and hydro-metallurgical processes (the so-called "slime of the slag"), usually containing considerable metal resources and nearly 70 wt % H2O inside. In this study, a facile leaching complexation method is proposed for the cleaner, efficient, and selective recovery of V, Cr, and Fe. After efficient leaching procedure in the H2SO4 solution, 94% V and 97% Fe were selectively precipitated out via the complexation with C5H10NNaS2. Subsequently, the V and Fe could be further separated through the dissociation in alkaline solution, in which the Fe(OH)(3) solid and Ca2V2O7 (with the addition of CaO) were generated, respectively. Furthermore, the complexing agent could be regenerated for next cycles, minimizing the potential secondary wastewater or solid waste formation. As a result, a cleaner and sustainable metal recovery method was developed, providing further understanding of the solution chemistry and separation technologies. |
| WOS关键词 | VANADIUM SLAG ; DITHIOCARBAMATE COMPLEXES ; SCR CATALYST ; EXTRACTION ; SEPARATION ; CHROMIUM ; CR(VI) ; V(V) ; IRON |
| 资助项目 | National Natural Science Foundation of China[51674230] ; National Natural Science Foundation of China[51604253] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000509432200025 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/38723]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Yang; Jin, Wei |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yang,Peng, Xuefeng,Fan, Bingqiang,et al. Sustainable Valuable Metal Recovery from the V-Cr-Fe Ternary Slime via Leaching-Selective Complexation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(2):958-965. |
| APA | Zhang, Yang.,Peng, Xuefeng.,Fan, Bingqiang.,Zang, Nan.,Zheng, Shili.,...&Jin, Wei.(2020).Sustainable Valuable Metal Recovery from the V-Cr-Fe Ternary Slime via Leaching-Selective Complexation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(2),958-965. |
| MLA | Zhang, Yang,et al."Sustainable Valuable Metal Recovery from the V-Cr-Fe Ternary Slime via Leaching-Selective Complexation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.2(2020):958-965. |
入库方式： OAI收割
来源：过程工程研究所
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