Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)
文献类型：期刊论文
| 作者 | Kikuchi, Shu2; Shoji, Ryoka2; Yoshida, Saki2; Kanehashi, Shinji2; Ma, Guang-Hui1; Ogino, Kenji2 |
| 刊名 | COLLOID AND POLYMER SCIENCE
 |
| 出版日期 | 2020-01-24 |
| 页码 | 11 |
| 关键词 | Core-shell Janus Phase separation Polymer blend Polymer particle Triphenylamine |
| ISSN号 | 0303-402X |
| DOI | 10.1007/s00396-020-04604-9 |
| 英文摘要 | We here report the facile fabrication of inverse core-shell and Janus structured particles consisting of poly(4-butyltriphenylamine) (PBTPA) and poly(methyl methacrylate) (PMMA) via a solvent evaporation from solution droplets of a polymer blend dispersed in an aqueous phase. Janus structured composite particles in which the PBTPA domain was partially coated by the PMMA domain were obtained using poly(vinyl alcohol) (PVA) as a suspension stabilizer. On the other hand, when sodium dodecyl sulfate (SDS) was added as a surfactant together with PVA, "inverse core-shell" particles in which the PMMA core was covered by the PBTPA shell were formed as well as Janus particles. TEM observation showed that the PMMA core was located at the center of the sphere and PBTPA layer has uniform thickness in inverse core-shell particles. The increase of the composition of PBTPA or the concentration of SDS increased the ratio of the inverse core-shell particles to the Janus ones. |
| WOS关键词 | PARTICLE MORPHOLOGY DEVELOPMENT ; SEEDED EMULSION POLYMERIZATION ; COMPOSITE-PARTICLES ; MOLECULAR-WEIGHT ; POLYMERS ; COPOLYMER ; FRACTURE ; RUBBER ; LIGHT ; SHAPE |
| WOS研究方向 | Chemistry ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000509157800001 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/38740]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Kanehashi, Shinji; Ogino, Kenji |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100080, Peoples R China 2.Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, 2-24-16 Nakacho, Koganei, Tokyo 1848588, Japan |
| 推荐引用方式 GB/T 7714 | Kikuchi, Shu,Shoji, Ryoka,Yoshida, Saki,et al. Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)[J]. COLLOID AND POLYMER SCIENCE,2020:11. |
| APA | Kikuchi, Shu,Shoji, Ryoka,Yoshida, Saki,Kanehashi, Shinji,Ma, Guang-Hui,&Ogino, Kenji.(2020).Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate).COLLOID AND POLYMER SCIENCE,11. |
| MLA | Kikuchi, Shu,et al."Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)".COLLOID AND POLYMER SCIENCE (2020):11. |
入库方式： OAI收割
来源：过程工程研究所
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