中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO

文献类型:期刊论文

作者Zhuang, Shengli2,4; Chen, Dong3; Liao, Lingwen2,4; Zhao, Yan2,4; Xia, Nan2,4; Zhang, Wenhao2,4; Wang, Chengming1; Yang, Jun3; Wu, Zhikun2,4
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2020-01-21
页码6
关键词cadmium CO2 reduction electrocatalysis gold nanoclusters two-phase anti-galvanic reduction
ISSN号1433-7851
DOI10.1002/anie.201912845
英文摘要Metal nanoclusters have recently attracted considerable attention, not only because of their special size range but also because of their well-defined compositions and structures. However, subtly tailoring the compositions and structures of metal nanoclusters for potential applications remains challenging. Now, a two-phase anti-galvanic reduction (AGR) method is presented for precisely tailoring Au-44(TBBT)(28) to produce Au47Cd2(TBBT)(31) nanoclusters with a hard-sphere random close-packed structure, exhibiting Faradaic efficiencies of up to 96 % at -0.57 V for the electrocatalytic reduction of CO2 to CO.
WOS关键词ANTI-GALVANIC REDUCTION ; THIOLATE-PROTECTED GOLD ; SILVER ; AU-25 ; NANOPARTICLES ; CLUSTERS ; ATOMS ; ELECTROREDUCTION
资助项目National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[21905284] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21706265] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21573212] ; National Natural Science Foundation of China[21573240] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; China Postdoctoral Science Foundation[Y94G4E356B] ; CASHIPS Director's Fund[BJPY2019A02] ; Key Program of 13th five-year plan, CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; National Key R&D Program of China[2017YFA0207302] ; Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences[MPCS-2019-A-09]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000508245500001
出版者WILEY-V C H VERLAG GMBH
资助机构National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; CASHIPS Director's Fund ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Key R&D Program of China ; Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences
源URL[http://ir.ipe.ac.cn/handle/122111/38779]  
专题中国科学院过程工程研究所
通讯作者Yang, Jun; Wu, Zhikun
作者单位1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
2.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
4.Chinese Acad Sci, CAS Ctr Excellence Nanosci, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys,Inst Solid State Phys, Hefei 230031, Peoples R China
推荐引用方式
GB/T 7714
Zhuang, Shengli,Chen, Dong,Liao, Lingwen,et al. Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020:6.
APA Zhuang, Shengli.,Chen, Dong.,Liao, Lingwen.,Zhao, Yan.,Xia, Nan.,...&Wu, Zhikun.(2020).Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,6.
MLA Zhuang, Shengli,et al."Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020):6.

入库方式: OAI收割

来源:过程工程研究所

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