Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO
文献类型:期刊论文
作者 | Zhuang, Shengli2,4; Chen, Dong3; Liao, Lingwen2,4; Zhao, Yan2,4; Xia, Nan2,4; Zhang, Wenhao2,4; Wang, Chengming1; Yang, Jun3; Wu, Zhikun2,4 |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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出版日期 | 2020-01-21 |
页码 | 6 |
关键词 | cadmium CO2 reduction electrocatalysis gold nanoclusters two-phase anti-galvanic reduction |
ISSN号 | 1433-7851 |
DOI | 10.1002/anie.201912845 |
英文摘要 | Metal nanoclusters have recently attracted considerable attention, not only because of their special size range but also because of their well-defined compositions and structures. However, subtly tailoring the compositions and structures of metal nanoclusters for potential applications remains challenging. Now, a two-phase anti-galvanic reduction (AGR) method is presented for precisely tailoring Au-44(TBBT)(28) to produce Au47Cd2(TBBT)(31) nanoclusters with a hard-sphere random close-packed structure, exhibiting Faradaic efficiencies of up to 96 % at -0.57 V for the electrocatalytic reduction of CO2 to CO. |
WOS关键词 | ANTI-GALVANIC REDUCTION ; THIOLATE-PROTECTED GOLD ; SILVER ; AU-25 ; NANOPARTICLES ; CLUSTERS ; ATOMS ; ELECTROREDUCTION |
资助项目 | National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[21905284] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21706265] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21573212] ; National Natural Science Foundation of China[21573240] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; China Postdoctoral Science Foundation[Y94G4E356B] ; CASHIPS Director's Fund[BJPY2019A02] ; Key Program of 13th five-year plan, CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; National Key R&D Program of China[2017YFA0207302] ; Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences[MPCS-2019-A-09] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000508245500001 |
出版者 | WILEY-V C H VERLAG GMBH |
资助机构 | National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; CASHIPS Director's Fund ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Key R&D Program of China ; Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences |
源URL | [http://ir.ipe.ac.cn/handle/122111/38779] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Yang, Jun; Wu, Zhikun |
作者单位 | 1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 2.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.Chinese Acad Sci, CAS Ctr Excellence Nanosci, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys,Inst Solid State Phys, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Zhuang, Shengli,Chen, Dong,Liao, Lingwen,et al. Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020:6. |
APA | Zhuang, Shengli.,Chen, Dong.,Liao, Lingwen.,Zhao, Yan.,Xia, Nan.,...&Wu, Zhikun.(2020).Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,6. |
MLA | Zhuang, Shengli,et al."Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO2 Reduction to CO".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020):6. |
入库方式: OAI收割
来源:过程工程研究所
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