Hierarchical porous carbon foam supported on carbon cloth as high-performance anodes for aqueous supercapacitors
文献类型:期刊论文
作者 | Zhang, Jie1,2; Li, Wenli1,2; Shifa, Tofik Ahmed3; Sun, Jiangbo2; Jia, Chuqiao2; Zhao, Yumin2; Cui, Yanbin1,2 |
刊名 | JOURNAL OF POWER SOURCES |
出版日期 | 2019-11-01 |
卷号 | 439页码:7 |
ISSN号 | 0378-7753 |
关键词 | Electro-etching Porous carbon foam Binder-free electrode High-voltage supercapacitor |
DOI | 10.1016/j.jpowsour.2019.227066 |
英文摘要 | Carbon anodes have been widely utilized for the fabrication of high-performance asymmetric supercapacitors. However, they generally suffer from unsatisfactory energy density due to low specific capacitance arising from inferior conductivity and insufficient ionic diffusion rate. Here a surface modification method is conducted after the annealing of ZIF-67 precursor to produce hydrophilic, porous and heteroatom-doped carbon foam. On top of enhanced area capacitance, widened voltage window of -1.3-0V (vs saturated calomel electrode) can be achieved through electrochemical reduction to suppress the hydrogen evolution reaction. The optimized reduced porous carbon foam on carbon cloth exhibits a maximum area capacitance of 1049 mF/cm(2) at an applied current density of 12 mA/cm(2) with excellent capacitance retention of 98.4% after 6000 charge-discharge cycles at 15 mA/cm(2). By well pairing with hierarchical MnO2/CC cathode, a 2.3 V asymmetric supercapacitor in neutral aqueous Na2SO4 electrolyte is assembled, which delivers an exceptional energy density of up to 10.07 mWh/cm(3). The procedure in this paper for carbonaceous material to simultaneously achieve considerable capacitance and enlarged voltage window can open up a wider prospect toward design of anodes for high-performance aqueous supercapacitor. |
WOS关键词 | METAL-ORGANIC FRAMEWORKS ; OPERATING VOLTAGE ; IN-SITU ; OXYGEN ; EFFICIENT ; NITROGEN ; HYBRID ; NANOPARTICLES ; FABRICATION ; ELECTRODES |
资助项目 | Fund of State Key Laboratory of Multiphase Complex Systems[MPCS-2019-A-03] ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences[COM2016A003] |
WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000494891700033 |
资助机构 | Fund of State Key Laboratory of Multiphase Complex Systems ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences |
源URL | [http://ir.ipe.ac.cn/handle/122111/39053] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Cui, Yanbin |
作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Lulea Univ Technol, Dept Engn Sci & Math, Expt Phys & Mat Sci Div, Lulea, Sweden |
推荐引用方式 GB/T 7714 | Zhang, Jie,Li, Wenli,Shifa, Tofik Ahmed,et al. Hierarchical porous carbon foam supported on carbon cloth as high-performance anodes for aqueous supercapacitors[J]. JOURNAL OF POWER SOURCES,2019,439:7. |
APA | Zhang, Jie.,Li, Wenli.,Shifa, Tofik Ahmed.,Sun, Jiangbo.,Jia, Chuqiao.,...&Cui, Yanbin.(2019).Hierarchical porous carbon foam supported on carbon cloth as high-performance anodes for aqueous supercapacitors.JOURNAL OF POWER SOURCES,439,7. |
MLA | Zhang, Jie,et al."Hierarchical porous carbon foam supported on carbon cloth as high-performance anodes for aqueous supercapacitors".JOURNAL OF POWER SOURCES 439(2019):7. |
入库方式: OAI收割
来源:过程工程研究所
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