中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Behavior and Kinetics of Drying, Pyrolysis, Gasification, and Combustion Tested by a Microfluidized Bed Reaction Analyzer for the Staged-Gasification Process

文献类型:期刊论文

作者Zeng, Xi1,2; Zhang, Jianling1; Adamu, Mohammed Haruna2; Wang, Fang1; Han, Zhennan3; Zheng, Qingxin4; Zhang, Lijuan1; Xu, Guangwen1,3
刊名ENERGY & FUELS
出版日期2020-02-01
卷号34期号:2页码:2553-2565
ISSN号0887-0624
DOI10.1021/acs.energyfuels.9b03707
英文摘要

In this research, a systematic analysis and comparison between the behavior and the kinetics of coal drying in Ar, coal pyrolysis in Ar, char gasification in CO2, and char combustion in air were conducted on a microfluidized bed reaction analyzer according to the isothermal method. To avoid the thermal decomposition of the coal particle at high temperature, the wet char sample with a moisture content of 20% was adopted to simulate the process of coal drying. For the tested experimental temperature in the range of 1123-1223 K, the process of coal pyrolysis in Ar can be finished in 10 s while the processes of char gasification in CO2, char combustion in air, and wet char drying in Ar were much longer, on a minute scale. The drying process spent most of the time in char gasification and combustion, all of which happened nearly simultaneously rather than subsequently in the actual gasifier. At 1123 K, the ratios of the maximum reaction rate between drying and gasification, combustion and gasification, and pyrolysis and combustion were 2.2, 34.0, and 225.0, respectively. For char combustion, the delayed phenomenon extended the whole reaction time and lowered the reaction rate significantly at a conversion above 0.6. Thus, the main limiting steps in the gasifier were char gasification and the delayed combustion. The calculated activation energies (E-a) for pyrolysis in Ar, drying in Ar, normal combustion in air, delayed combustion in air, and gasification in CO2 were 30.5, 67.0, 56.4, 143.5, and 176.4 kJ/mol, respectively. Finally, from the viewpoint of the reaction behavior and kinetics, some suggestions were provided for the design and operation of the fluidized bed two-stage gasification process.

WOS关键词Coal Char Combustion ; Micro Fluidized-bed ; Co2 Gasification ; Thermogravimetric Analysis ; Biomass Gasification ; Moisture-content ; Herb Residue ; Performance ; Fundamentals ; Operation
资助项目National Key Scientific Equipment Research and Development Program[2018YFF01011401]
WOS研究方向Energy & Fuels ; Engineering
语种英语
WOS记录号WOS:000518215400145
出版者AMER CHEMICAL SOC
资助机构National Key Scientific Equipment Research and Development Program
源URL[http://ir.ipe.ac.cn/handle/122111/39419]  
专题中国科学院过程工程研究所
通讯作者Zhang, Jianling; Wang, Fang
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Shenyang Univ Chem Technol, Minist Educ, Key Lab Resources Chem & Mat, Shenyang 110142, Peoples R China
4.Tohoku Univ, Res Ctr Supercrit Fluid Technol, Grad Sch Engn, Sendai, Miyagi 9808579, Japan
推荐引用方式
GB/T 7714
Zeng, Xi,Zhang, Jianling,Adamu, Mohammed Haruna,et al. Behavior and Kinetics of Drying, Pyrolysis, Gasification, and Combustion Tested by a Microfluidized Bed Reaction Analyzer for the Staged-Gasification Process[J]. ENERGY & FUELS,2020,34(2):2553-2565.
APA Zeng, Xi.,Zhang, Jianling.,Adamu, Mohammed Haruna.,Wang, Fang.,Han, Zhennan.,...&Xu, Guangwen.(2020).Behavior and Kinetics of Drying, Pyrolysis, Gasification, and Combustion Tested by a Microfluidized Bed Reaction Analyzer for the Staged-Gasification Process.ENERGY & FUELS,34(2),2553-2565.
MLA Zeng, Xi,et al."Behavior and Kinetics of Drying, Pyrolysis, Gasification, and Combustion Tested by a Microfluidized Bed Reaction Analyzer for the Staged-Gasification Process".ENERGY & FUELS 34.2(2020):2553-2565.

入库方式: OAI收割

来源:过程工程研究所

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