Density, Viscosity, and Conductivity of [VAIM][TFSI] in Mixtures for Lithium-Ion Battery Electrolytes
文献类型：期刊论文
| 作者 | Cai, Yingjun1,2; von Solms, Nicolas1; Zhang, Suojiang2; Thomsen, Kaj1 |
| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| 出版日期 | 2020-02-01 |
| 卷号 | 65期号:2页码:495-502 |
| ISSN号 | 0021-9568 |
| DOI | 10.1021/acs.jced.9b00648 |
| 英文摘要 | A novel unsaturated and amide -based ionic liquid, [VAIM] [TFSI] (3-(2-amino-2-oxoethyl)-1-vinylimidazolium bis(trifluoromethylsulfonyl)amide), was synthesized using a two-step method. Its structure was confirmed by nuclear magnetic resonance, and its water content was determined by Karl Fischer titration to be below 0.03 wt %. The density, viscosity, and conductivity of the pure ionic liquid and its binary mixtures with acetonitrile were measured at various temperatures and at ambient pressure. Both the density and viscosity increase with the mole fraction of the ionic liquid and decrease with decreasing temperature. Excess molar volumes and viscosity deviations were calculated from the experimental results. The electrical conductivities in mixtures with different contents of the ionic liquid were investigated at different temperatures. The highest conductivity of binary mixtures is achieved at 0.07 mole fraction, with a value of similar to 3.32 S.m(-1) at 298.15 K. The conductivity of an electrolyte consisting of acetonitrile, LiTFSI, and the ionic liquid was measured to determine the optimal ionic liquid content. The suggested concentration is 3 wt% ionic liquid in this electrolyte, giving a conductivity of similar to 4.11 S.m(-1) at 298.15 K. |
| WOS关键词 | EXCESS PROPERTIES ; LIQUID ; TEMPERATURE ; POLYMER ; STABILITY ; CATIONS ; TETRAFLUOROBORATE ; EQUILIBRIUM ; SEPARATION ; TRANSPORT |
| 资助项目 | China Scholarship Council ; Department of Chemical Engineering, Technical University of Denmark ; Major Program of National Natural Science Foundation of China[21890762] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC011] |
| WOS研究方向 | Thermodynamics ; Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000514221900018 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | China Scholarship Council ; Department of Chemical Engineering, Technical University of Denmark ; Major Program of National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/39731]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Thomsen, Kaj |
| 作者单位 | 1.Tech Univ Denmark, CERE, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai, Yingjun,von Solms, Nicolas,Zhang, Suojiang,et al. Density, Viscosity, and Conductivity of [VAIM][TFSI] in Mixtures for Lithium-Ion Battery Electrolytes[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2020,65(2):495-502. |
| APA | Cai, Yingjun,von Solms, Nicolas,Zhang, Suojiang,&Thomsen, Kaj.(2020).Density, Viscosity, and Conductivity of [VAIM][TFSI] in Mixtures for Lithium-Ion Battery Electrolytes.JOURNAL OF CHEMICAL AND ENGINEERING DATA,65(2),495-502. |
| MLA | Cai, Yingjun,et al."Density, Viscosity, and Conductivity of [VAIM][TFSI] in Mixtures for Lithium-Ion Battery Electrolytes".JOURNAL OF CHEMICAL AND ENGINEERING DATA 65.2(2020):495-502. |
入库方式： OAI收割
来源：过程工程研究所
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