The Structure Effect on the Activity and Strength of an Industrial Honeycomb Catalyst Derived from Different Ti Sources
文献类型：期刊论文
| 作者 | Li, Yunjia1,2; Abubakar, Abdullahi1,2; Lin Huangfu1,2; Li, Changming1; Li, Jianling1; Yu, Jian1; Gao, Shiqiu1 |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2020 |
| 卷号 | 10期号:1页码:11 |
| 关键词 | honeycomb catalyst DeNO(x) efficiency strength structure effect |
| DOI | 10.3390/catal10010042 |
| 英文摘要 | A new honeycomb production process was proposed with both filter cake (from hydrothermal treatment of metatitanic acid) and industrial titanium dioxide as Ti sources. The strength of the obtained pilot product was comparable with the current industrial honeycomb product from only filter cake, but its denitration (DeNO(x)) efficiency was elevated up to 15 percentage points. Multiple characterizations revealed the filter cake and industrial titanium dioxide to be composed of primary particles and secondary particles, respectively, and the introduced secondary particles from industrial titanium dioxide resulted in increased specific surface area and pore size/volume, facilitating the exposure of more active sites with improved activity. Moreover, a positive correlation property was found between the honeycomb strength and crystallinity for the samples from different titanium sources. The filter cake with rich hydroxyl groups and weak crystallinity could be fused more easily among these primary particles to have a higher strength than industrial titanium dioxide, and the primary particle of the filter cake could fill the pile pore of industrial titanium dioxide and act as a solid phase binder to acquire good strength for the honeycomb using both the filter cake and titanium dioxide as Ti sources. The improved honeycomb product with good activity and strength may have more widespread application for the purification of low temperature flue gas in industry. |
| WOS关键词 | REDUCTION ; NO ; DECOMPOSITION ; NH4HSO4 ; DENO(X) ; GAS |
| 资助项目 | National Key Research and Development Program of China[2017YFB0310403] ; Natural Science Foundation of China[21601192] ; Natural Science Foundation of China[21878310] ; State Key Laboratory of Multi-phase Complex Systems[MPCS-2019-0-03] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000516825000042 |
| 出版者 | MDPI |
| 资助机构 | National Key Research and Development Program of China ; Natural Science Foundation of China ; State Key Laboratory of Multi-phase Complex Systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/39790]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Changming; Yu, Jian |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yunjia,Abubakar, Abdullahi,Lin Huangfu,et al. The Structure Effect on the Activity and Strength of an Industrial Honeycomb Catalyst Derived from Different Ti Sources[J]. CATALYSTS,2020,10(1):11. |
| APA | Li, Yunjia.,Abubakar, Abdullahi.,Lin Huangfu.,Li, Changming.,Li, Jianling.,...&Gao, Shiqiu.(2020).The Structure Effect on the Activity and Strength of an Industrial Honeycomb Catalyst Derived from Different Ti Sources.CATALYSTS,10(1),11. |
| MLA | Li, Yunjia,et al."The Structure Effect on the Activity and Strength of an Industrial Honeycomb Catalyst Derived from Different Ti Sources".CATALYSTS 10.1(2020):11. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。