Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives
文献类型：期刊论文
| 作者 | Cherevan, Alexey S.4; Nandan, Sreejith P.4; Roger, Isolda3; Liu, Rongji2,3; Streb, Carsten1,3; Eder, Dominik4 |
| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2020-04-01 |
| 卷号 | 7期号:8页码:23 |
| 关键词 | charge transfer composites heterogenization molecular metal oxides substrates |
| DOI | 10.1002/advs.201903511 |
| 英文摘要 | Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of structures and functionalities, making them one of the most versatile classes of inorganic molecular materials. They have attracted widespread attention in homogeneous catalysis. Due to the challenges associated with their aggregation, precipitation, and degradation under operational conditions and to extend their scope of applications, various strategies of depositing POMs on heterogeneous substrates have been developed. Recent ground-breaking developments in the materials chemistry of supported POM composites are summarized and links between molecular-level understanding of POM-support interactions and macroscopic effects including new or optimized reactivities, improved stability, and novel function are established. Current limitations and future challenges in studying these complex composite materials are highlighted, and cutting-edge experimental and theoretical methods that will lead to an improved understanding of synergisms between POM and support material from the molecular through to the nano- and micrometer level are discussed. Future development in this fast-moving field is explored and emerging fields of research in POM heterogenization are identified. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; GRAPHITIC CARBON NITRIDE ; WATER OXIDATION CATALYST ; HIGHLY EFFICIENT ; KEGGIN-TYPE ; TIO2 NANOPARTICLES ; ELECTRON-TRANSFER ; PHOTOCATALYTIC DEGRADATION ; HETEROGENEOUS CATALYST ; COMPOSITE ELECTRODES |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | WILEY |
| WOS记录号 | WOS:000529216500007 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/40365]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Cherevan, Alexey S.; Streb, Carsten; Eder, Dominik |
| 作者单位 | 1.Helmholtz Inst Ulm, Helmholtzstr 11, D-89081 Ulm, Germany 2.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 3.Ulm Univ, Inst Inorgan Chem 1, Albert Einstein Allee 11, D-89081 Ulm, Germany 4.Vienna Univ Technol, Inst Mat Chem, Getreidemarkt 9-BC-02, A-1060 Vienna, Austria |
| 推荐引用方式 GB/T 7714 | Cherevan, Alexey S.,Nandan, Sreejith P.,Roger, Isolda,et al. Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives[J]. ADVANCED SCIENCE,2020,7(8):23. |
| APA | Cherevan, Alexey S.,Nandan, Sreejith P.,Roger, Isolda,Liu, Rongji,Streb, Carsten,&Eder, Dominik.(2020).Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives.ADVANCED SCIENCE,7(8),23. |
| MLA | Cherevan, Alexey S.,et al."Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives".ADVANCED SCIENCE 7.8(2020):23. |
入库方式： OAI收割
来源：过程工程研究所
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