Dual-functionalized protic ionic liquids for efficient absorption of NH3 through synergistically physicochemical interaction
文献类型：期刊论文
| 作者 | Yuan Lei2,3; Zhang Xiangping1,2,3; Ren Baozeng3; Yang Yingliang2,3; Bai Yinge2; Bai Lu2; Gao Hongshuai2; Zeng Shaojuan2 |
| 刊名 | JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
 |
| 出版日期 | 2020-06-01 |
| 卷号 | 95期号:6页码:1815-1824 |
| 关键词 | dual-functionalized protic ILs (DPILs) NH3 absorption synergistically physicochemical interaction selectivity |
| ISSN号 | 0268-2575 |
| DOI | 10.1002/jctb.6381 |
| 英文摘要 | BACKGROUND Ionic liquids have become promising media for the treatment of tail gases containing ammonia (NH3), which causes serious environmental problems and threatens human health. RESULTS In this work, four dual-functionalized protic ionic liquids (DPILs) [C(n)OHim]X (n = 1, 2; X = [NTf2](-), [BF4](-), [SCN](-)) with both weak acidity proton and hydroxyl group were designed and synthesized for enhanced NH3 separation. Among them, the maximum NH3 molar solubility of 3.11 mol NH3 mol(-1) IL was achieved in [EtOHim][NTf2] at 40 degrees C and atmospheric pressure, and the highest mass solubility of NH3 could be 0.221 g NH3 g(-1) IL in [EtOHim][SCN]; this is the highest value of any absorbent ever reported under the same conditions. Not only superior NH3 solubility, along with excellent selectivity of NH3/CO2 (65) and NH3/N-2 (104), but also outstanding recyclability was exhibited in DPILs. CONCLUSIONS The highly efficient performance of NH3 absorption by DPILs was ascribed to the synergistically physicochemical interaction between weak acidity proton, hydroxyl group and NH3, which was confirmed through both spectrum analysis and quantum chemical calculations. This work implied that DPILs have great potentials in NH3 separation and recovery of NH3-containing tail gases. (c) 2020 Society of Chemical Industry |
| WOS关键词 | DEEP EUTECTIC SOLVENTS ; HIGHLY EFFICIENT ; REVERSIBLE CAPTURE ; HYDROGEN-SULFIDE ; CARBON-DIOXIDE ; CO2 CAPTURE ; AMMONIA ; SO2 ; SOLUBILITY ; H2S |
| WOS研究方向 | Biotechnology & Applied Microbiology ; Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000530688600022 |
| 出版者 | WILEY |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/40374]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Gao Hongshuai; Zeng Shaojuan |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Chem & Engn, Beijing, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn,Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Zhengzhou Univ, Coll Chem & Engn, Zhengzhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan Lei,Zhang Xiangping,Ren Baozeng,et al. Dual-functionalized protic ionic liquids for efficient absorption of NH3 through synergistically physicochemical interaction[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,2020,95(6):1815-1824. |
| APA | Yuan Lei.,Zhang Xiangping.,Ren Baozeng.,Yang Yingliang.,Bai Yinge.,...&Zeng Shaojuan.(2020).Dual-functionalized protic ionic liquids for efficient absorption of NH3 through synergistically physicochemical interaction.JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,95(6),1815-1824. |
| MLA | Yuan Lei,et al."Dual-functionalized protic ionic liquids for efficient absorption of NH3 through synergistically physicochemical interaction".JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY 95.6(2020):1815-1824. |
入库方式： OAI收割
来源：过程工程研究所
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