Effects of MoO3 and CeO2 doping on the decomposition and reactivity of NH4HSO4 on V2O5/TiO2 catalysts
文献类型：期刊论文
| 作者 | Xu, Wenqing2,3; Gao, Lei1,3; Yang, Yang3; Zhu, Tingyu2,3; Qi, Guisheng1 |
| 刊名 | ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
 |
| 出版日期 | 2020-05-25 |
| 页码 | 11 |
| 关键词 | Ammonium bisulfate Decomposition Low-temperature SCR MoO3 doping CeO2 doping V2O5 TiO2 catalyst |
| ISSN号 | 0944-1344 |
| DOI | 10.1007/s11356-020-09343-6 |
| 英文摘要 | The deposition of NH4HSO4 on catalysts is one of the key issues for selective catalytic reduction of NOx. In this study, NH4HSO4 was preloaded on catalysts, and the effects of MoO3 and CeO2 doping on the decomposition and reactivity of NH4HSO4 on V2O5/TiO2 catalysts are studied. The results show that the introduction of MoO3 and CeO2 significantly promoted NOx conversion on the V2O5/TiO2 catalysts. Doping with MoO3 could effectively enhance the S and H2O resistance of the catalysts. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis indicate that it is the strong chemical interactions between NH4HSO4 and the catalysts that are adverse to the decomposition of NH4HSO4. However, doping with MoO3 apparently inhibits these interactions, which significantly decrease the decomposition temperature of NH4HSO4. In situ FTIR experiments show that the NH4+ in preloaded NH4HSO4 could react with gaseous NO on catalysts, and doping with MoO3 could facilitate the reaction rate. |
| WOS关键词 | SIMULTANEOUS REMOVAL ; SCR PERFORMANCE ; SO2 RESISTANCE ; NO REDUCTION ; TEMPERATURE ; NH3 ; BEHAVIORS ; NH3-SCR ; OXIDES ; CERIA |
| 资助项目 | National Key Research and Development Program of China[2016YFC0204103] ; Key Research and Development Program of Shanxi province[201703D111018] |
| WOS研究方向 | Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000535460400009 |
| 出版者 | SPRINGER HEIDELBERG |
| 资助机构 | National Key Research and Development Program of China ; Key Research and Development Program of Shanxi province |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/40872]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xu, Wenqing |
| 作者单位 | 1.North Univ China, Shanxi Prov Key Lab Higee Oriented Chem Engn, Taiyuan 030051, Shanxi, Peoples R China 2.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China 3.Chinese Acad Sci, Res Ctr Proc Pollut Control, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Wenqing,Gao, Lei,Yang, Yang,et al. Effects of MoO3 and CeO2 doping on the decomposition and reactivity of NH4HSO4 on V2O5/TiO2 catalysts[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2020:11. |
| APA | Xu, Wenqing,Gao, Lei,Yang, Yang,Zhu, Tingyu,&Qi, Guisheng.(2020).Effects of MoO3 and CeO2 doping on the decomposition and reactivity of NH4HSO4 on V2O5/TiO2 catalysts.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,11. |
| MLA | Xu, Wenqing,et al."Effects of MoO3 and CeO2 doping on the decomposition and reactivity of NH4HSO4 on V2O5/TiO2 catalysts".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2020):11. |
入库方式： OAI收割
来源：过程工程研究所
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