中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A new strategy for enhancing the room temperature conductivity of solid-state electrolyte by using a polymeric ionic liquid

文献类型:期刊论文

作者Sha, Yifan1,2; Dong, Tao1; Zhao, Qiu1,2; Zheng, Hongshuai1; Wen, Xinge1; Chen, Shimou1; Zhang, Suojiang1
刊名IONICS
出版日期2020-06-09
页码10
关键词Polymer Electrolyte Polymeric Ionic Liquid Solid-state Lithium-ion Batteries
ISSN号0947-7047
DOI10.1007/s11581-020-03638-x
英文摘要

An ether-functionalized polymeric ionic liquid poly(methyl methacrylate-1-vinyl-3-methoxyl-ethyl-imidazolium bis(trifluoromethanesulfonyl)imide) P(MMA-co-VIm(1O2)) (TFSI) polymeric ionic liquid (PIL) was successfully synthesized, characterized, and used as polymer matrix. The performances of solid polymer electrolytes membrane were measured through blending with poly(vinylidene fluoride-cohexafluoropropylene) (PVDF-HFP) and 1-propyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide ([Pyr(13)][TFSI]). The ionic conductivity of polymer electrolytes was optimized up to 5.10 x 10(-4)S cm(-1)at 25 degrees C, and a wide electrochemical window of 5.23 V vs Li/Li(+)could be obtained. Moreover, the polymer electrolytes showed excellent cycle performance for Li/LiFePO(4)cell at both 25 degrees C and 60 degrees C, demonstrating the capability of being a promising candidate for the application of solid-state lithium-ion batteries.

WOS关键词Pvdf-hfp ; Poly(Ionic Liquid)s ; Guanidinium Cations ; Battery ; Performance ; Challenges ; Issues
资助项目National Key R&D Program of China[2017YFB0102000] ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China[21921005] ; National Natural Science Foundation of China[51922099] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC011]
WOS研究方向Chemistry ; Electrochemistry ; Physics
语种英语
WOS记录号WOS:000539476700002
出版者SPRINGER HEIDELBERG
资助机构National Key R&D Program of China ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS
源URL[http://ir.ipe.ac.cn/handle/122111/41140]  
专题中国科学院过程工程研究所
通讯作者Zhang, Suojiang
作者单位1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn,CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Peoples R China
推荐引用方式
GB/T 7714
Sha, Yifan,Dong, Tao,Zhao, Qiu,et al. A new strategy for enhancing the room temperature conductivity of solid-state electrolyte by using a polymeric ionic liquid[J]. IONICS,2020:10.
APA Sha, Yifan.,Dong, Tao.,Zhao, Qiu.,Zheng, Hongshuai.,Wen, Xinge.,...&Zhang, Suojiang.(2020).A new strategy for enhancing the room temperature conductivity of solid-state electrolyte by using a polymeric ionic liquid.IONICS,10.
MLA Sha, Yifan,et al."A new strategy for enhancing the room temperature conductivity of solid-state electrolyte by using a polymeric ionic liquid".IONICS (2020):10.

入库方式: OAI收割

来源:过程工程研究所

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