Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts
文献类型：期刊论文
| 作者 | Zhang, Jimei3,4; Tian, Fuping2; Chen, Junwen1; Shi, Yanchun3; Cao, Hongbin3; Ning, Pengge3; Sun, Shanshan3; Xie, Yongbing3 |
| 刊名 | FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
 |
| 出版日期 | 2020-06-11 |
| 页码 | 11 |
| 关键词 | aqueous-phase hydrodeoxygenation phenol hydrocarbons Ni/HIM-5 bi-functional catalyst |
| ISSN号 | 2095-0179 |
| DOI | 10.1007/s11705-020-1932-y |
| 英文摘要 | A series of Ni/HZSM-5 and Ni/HIM-5 bi-functional catalysts were synthesized and applied to the aqueous-phase hydrodeoxygenation (HDO) of phenol. The Ni dispersibility and particle sizes were shown to be directly related to the porosity and crystal sizes of the parent zeolites, which further influenced the catalytic performances. The large pores and small crystal sizes of the parent zeolites were beneficial for dispersing Ni and forming small Ni particles, and the corresponding Ni/zeolite catalyst exhibited a higher phenol conversion and selectivity towards hydrocarbons. Importantly, the Ni/HIM-5 bi-functional catalyst exhibited a high activity (98.3%) and high selectivity for hydrocarbons (98.8%) when heated at 220 degrees C for 1 h and is thus a new potential catalyst for the HDO of phenolics to form hydrocarbons in the aqueous phase. |
| WOS关键词 | MODEL-COMPOUND ; PALMITIC ACID ; SUPPORTED NI ; HYDRODEOXYGENATION ; LIGNIN ; BIOMASS ; PYROLYSIS ; HYDROCARBONS ; NI/HZSM-5 ; GUAIACOL |
| 资助项目 | National Natural Science Foundation of China[21908225] ; National Key Research and Development Program of China[2016YFB0600505] ; Youth Innovation Promotion Association, CAS[2014037] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000539784400001 |
| 出版者 | SPRINGER |
| 资助机构 | National Natural Science Foundation of China ; National Key Research and Development Program of China ; Youth Innovation Promotion Association, CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/41144]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xie, Yongbing |
| 作者单位 | 1.SINOPEC, Res Inst Petr Proc, State Key Lab Catalyt Mat & React Engn, Beijing 100083, Peoples R China 2.Dalian Univ Technol, Coll Chem, Dalian 116024, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 4.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jimei,Tian, Fuping,Chen, Junwen,et al. Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts[J]. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,2020:11. |
| APA | Zhang, Jimei.,Tian, Fuping.,Chen, Junwen.,Shi, Yanchun.,Cao, Hongbin.,...&Xie, Yongbing.(2020).Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts.FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,11. |
| MLA | Zhang, Jimei,et al."Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts".FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING (2020):11. |
入库方式： OAI收割
来源：过程工程研究所
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