Ethers as hydrogen sources in BF3·OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons
文献类型：期刊论文
| 作者 | Li, Jiaqiang1; Liu, Qing1; Shen, Hang1; Huang, Ruofeng1; Zhang, Xiaohui1; Xiong, Yan1,2; Chen, Changguo1 |
| 刊名 | RSC Advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:104页码:85291-85295 |
| DOI | 10.1039/c5ra14775a |
| 英文摘要 | A novel ether/BF3 reductive system has been described, in which diphenylmethanols and their ether and ester derivatives are used as starting materials. Reductions are performed in ether under reflux and an argon atmosphere, and the addition of extra water is beneficial to this reduction. A series of alkanes are able to be prepared with good to excellent yields. A deuterated experiment exhibits that the reductive hydrogen is generated from ether. The mechanism is discussed in detail to explain the observed reactivity. © 2015 The Royal Society of Chemistry. |
| 电子版国际标准刊号 | 20462069 |
| 语种 | 英语 |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/9924]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 作者单位 | 1.School of Chemistry and Chemical Engineering, Chongqing University, Chongqing; 400044, China; 2.Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Science, Chongqing; 400714, China |
| 推荐引用方式 GB/T 7714 | Li, Jiaqiang,Liu, Qing,Shen, Hang,et al. Ethers as hydrogen sources in BF3·OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons[J]. RSC Advances,2015,5(104):85291-85295. |
| APA | Li, Jiaqiang.,Liu, Qing.,Shen, Hang.,Huang, Ruofeng.,Zhang, Xiaohui.,...&Chen, Changguo.(2015).Ethers as hydrogen sources in BF3·OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons.RSC Advances,5(104),85291-85295. |
| MLA | Li, Jiaqiang,et al."Ethers as hydrogen sources in BF3·OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons".RSC Advances 5.104(2015):85291-85295. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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