Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines
文献类型：期刊论文
| 作者 | Zhao, Yulei; Guo, Xuqiang; Si, Zhiyao; Hu, Yanan; Sun, Ying; Liu, Yunlin; Ji, Zhongyin; You, Jinmao
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| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
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| 出版日期 | 2020 |
| 卷号 | 85期号:20 |
| 英文摘要 | A methodology employing CO2, amines, and phenylsilane was discussed to access aryl- or alkyl-substituted urea derivatives. This procedure was characterized by adopting hydrosilane to promote the formation of ureas directly, without the need to prepare silylamines in advance. Control reactions suggested that FeCl3 was a favorable additive for the generation of ureas, and this 1,5,7-triazabicyclo[4.4.0] dec-5-ene-catalyzed reaction might proceed through nucleophilic addition, silicon migration, and the subsequent formal substitution of silylcarbamate. |
| 源URL | [http://210.75.249.4/handle/363003/60225]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Zhao, Yulei,Guo, Xuqiang,Si, Zhiyao,et al. Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines[J]. JOURNAL OF ORGANIC CHEMISTRY,2020,85(20). |
| APA | Zhao, Yulei.,Guo, Xuqiang.,Si, Zhiyao.,Hu, Yanan.,Sun, Ying.,...&You, Jinmao.(2020).Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines.JOURNAL OF ORGANIC CHEMISTRY,85(20). |
| MLA | Zhao, Yulei,et al."Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines".JOURNAL OF ORGANIC CHEMISTRY 85.20(2020). |
入库方式： OAI收割
来源：西北高原生物研究所
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