One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones
文献类型：期刊论文
| 作者 | Zhao, Yulei; Liu, Xu; Zheng, Lijun; Du, Yulan; Shi, Xinrui; Liu, Yunlin; Yan, Zhengquan; You, Jinmao ; Jiang, Yuanye
|
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2020 |
| 卷号 | 85期号:2 |
| 英文摘要 | One-pot methylenation-cyclization employing two molecules of CO2 with enaminones and primary aromatic amines was discussed for the first time to access cyclized products. This 1,5,7-triazabicyclo[4.4.0]dec-5-ene and ZnCl2-catalyzed procedure was characterized by the selective conversion of two molecules of CO2 into methylene groups in a multicomponent cyclization reaction. According to the computational study and control experiments, the reaction might proceed through the generation of bis(silyl)acetal and condensation of arylamine and aza-Diels-Alder processes. Moreover, the resulting products will probably be potential organic building blocks with adjustable photophysical properties. |
| 源URL | [http://210.75.249.4/handle/363003/60437]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Zhao, Yulei,Liu, Xu,Zheng, Lijun,et al. One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones[J]. JOURNAL OF ORGANIC CHEMISTRY,2020,85(2). |
| APA | Zhao, Yulei.,Liu, Xu.,Zheng, Lijun.,Du, Yulan.,Shi, Xinrui.,...&Jiang, Yuanye.(2020).One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones.JOURNAL OF ORGANIC CHEMISTRY,85(2). |
| MLA | Zhao, Yulei,et al."One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones".JOURNAL OF ORGANIC CHEMISTRY 85.2(2020). |
入库方式： OAI收割
来源：西北高原生物研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。