Hybrid polymer-based solar cells with metal oxides as the main electron acceptor and transporter
文献类型：期刊论文
| 作者 | Liu ZW(刘长文)1; Zhou X(周讯)1; Yue WJ(岳文瑾)2; Wang MT(王命泰)1 ; Qiu ZL(邱泽亮)1; Meng WL(孟维利)1; Chen JW(陈俊伟)1; Qi JJ(齐娟娟)1; Dong C(董超)1
|
| 刊名 | ACTA PHYSICA SINICA
 |
| 出版日期 | 2015 |
| 卷号 | 64 |
| 关键词 | MODULATED PHOTOCURRENT SPECTROSCOPY OPEN-CIRCUIT VOLTAGE POWER CONVERSION EFFICIENCY 25TH ANNIVERSARY ARTICLE ALIGNED ZNO NANORODS PHOTOVOLTAIC DEVICES RECOMBINATION KINETICS ORGANIC PHOTOVOLTAICS CHARGE-TRANSPORT LIGHT-INTENSITY solar cell metal oxide conjugated polymer transport dynamics |
| ISSN号 | 1000-3290 |
| 其他题名 | Hybrid polymer-based solar cells with metal oxides as the main electron acceptor and transporter |
| 英文摘要 | Hybrid polymer-based solar cells (HPSCs) that use conjugate polymers as electron donor (D) and inorganic semiconductor nanocrystals as electron acceptor (A) are novel photovoltaic devices. HPSCs integrate the properties of organic polymer (flexibility, ease of film formation, high absorption coefficient) and inorganic nanostructures (high electron mobility, high electron affinity, and good stability), and have the extra advantages, such as the rich sources of synthesized nanostructures by wet chemistry, tunable and complementary properties of assembled components, solution-processibility on a large scale at low cost and light-weight, etc. Amongst various inorganic semiconductor materials, the nanostructured metal oxides are the promising electron acceptors for HPSCs, because they are environment-friendly, transparent in visible spectrum and easy to be synthesized. After a brief introduction to the current research status, working principles, device architecture, steady-state and dynamic characterizations of HPSCs, this paper mainly reviews our recent research advances in the HPSCs using ZnO and TiO2 nanostructures as main electron acceptor and transporter, with emphasis on the theoretical models for charge carrier transport dynamics, design and preparation of efficient materials and devices, and the device performance related with nanostructural characteristics. Finally, the main challenges in the development of efficient HPSCs in basic researches and practical applications are also discussed. The main conclusions from our studies are summarized as follows: (i) IMPS and IMVS are powerful dynamic photoelectrochemical methods for studying the charge transport dynamics in HPSCs, and our theoretical models enable the IMPS to serve as an effective tool for the mechanistic characterization and optimization of HPSC devices. (ii) Using a multicomponent photoactive layer with complementary properties is an effective strategy to achieve efficient HPSCs. (iii) Using the complementary property of components, enhancing the dissociation efficiency of excitons, and improving the transport properties of the acceptor channels with reduced energy loss to increase collection efficiency all are the effective measures to access a high photocurrent generation in HPSCs. (iv) The band levels of components in the photoactive layer of HPSCs are aligned into type II heterojunctions, in which the nanostructured component with the lowest conduction band edge acts as the main acceptor/transporter; the maximum open-circuit voltage (V-oc) in HPSCs is determined by the energy difference between the highest occupied molecular orbital (HOMO) level of conjugated polymer and the conduction band edge of the main acceptor, but the V-oc in practical devices correlates strongly with the quasi-Fermi levels of the electrons in the main acceptor and the holes in the polymer. While passivating the surface defects on the main acceptor, increasing spatial e-h separation, and enhancing the electron density in conduction band of the main acceptor will facilitate the increase in V-oc. (v) There is no direct correlation among V-oc, photogenerated voltage (V-ph) and electron lifetime (tau(e)), and they may change in the same or the opposite trend when the same or different factors affect them, therefore one should get insight into the intrinsic factors that influence them when discussing the changes in V-oc, V-ph and tau(e) that are subject to nanostructural characteristics. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:5358502 |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/96786]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 作者单位 | 1.中国科学院等离子体物理研究所 2.中国科学院等离子体物理研究所 3.安徽工程大学生物与化学工程学院 4.中国科学院等离子体物理研究所 5.中国科学院等离子体物理研究所 6.中国科学院等离子体物理研究所 7.中国科学院等离子体物理研究所 8.中国科学院等离子体物理研究所 9.中国科学院等离子体物理研究所 |
| 推荐引用方式 GB/T 7714 | Liu ZW,Zhou X,Yue WJ,et al. Hybrid polymer-based solar cells with metal oxides as the main electron acceptor and transporter[J]. ACTA PHYSICA SINICA,2015,64. |
| APA | 刘长文.,周讯.,岳文瑾.,王命泰.,邱泽亮.,...&董超.(2015).Hybrid polymer-based solar cells with metal oxides as the main electron acceptor and transporter.ACTA PHYSICA SINICA,64. |
| MLA | 刘长文,et al."Hybrid polymer-based solar cells with metal oxides as the main electron acceptor and transporter".ACTA PHYSICA SINICA 64(2015). |
入库方式： OAI收割
来源：合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。