中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Experimental Studies on Three-Dimensional Fluorescence Spectral of Mineral Oil in Ethanol

文献类型:期刊论文

作者Xiao X(肖雪)1; Zhang YJ(张玉钧)1; Wang ZG(王志刚)1; Jin D(金丹)1; Yin GF(殷高方)1; Zhao NJ(赵南京)1; Liu WQ(刘文清)1
刊名SPECTROSCOPY AND SPECTRAL ANALYSIS
出版日期2010
卷号30
关键词WATER Mineral oil Three-dimensional fluorescence Scattering
ISSN号1000-0593
其他题名Experimental Studies on Three-Dimensional Fluorescence Spectral of Mineral Oil in Ethanol
英文摘要Three-dimensional excitation-emission matrix (EEM) fluorescence spectroscopy was applied to characterize the mineral oil in ethanol. In the paper, a simple way of treating the first-order Rayleigh, Raman and second-order Rayleigh scatter is used involving subtracting an EEM of a solvent blank, and removing and replacing the values with zeros. The corrected results showed that the characteristic three-dimensional fluorescence spectra of mineral oil were as follows; there was one mainly peak in the fluorescence spectrum of the kerosene, and the peak was identified at excitation/emission wavelengths (Ex/Em) of 270/290 nm; there were two intense fluorescence peaks in the fluorescence spectrum of 0# diesel, located at (Ex/Em) of 240/344 nm and 270/362 nm respectively; there were several fluorescence peaks in the fluorescence spectrum of lubricating oil, with the two intense peaks located at (Ex/Em) of 240/348 nm and 258/358 nm respectively. Furthermore, the relation between the relative fluorescence intensity and the concentration of mineral oil was studied, and the sensitivity and the limitation of detection of the method were also analyzed. The results of this study show that the method of three-dimensional fluorescence can be used to detect the low concentration of oil.
语种英语
CSCD记录号CSCD:3913788
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/100629]  
专题中国科学院合肥物质科学研究院
作者单位1.中国科学院安徽光学精密机械研究所
2.中国科学院安徽光学精密机械研究所
3.中国科学院安徽光学精密机械研究所
4.中国科学院安徽光学精密机械研究所
5.中国科学院安徽光学精密机械研究所
6.中国科学院安徽光学精密机械研究所
7.中国科学院安徽光学精密机械研究所
推荐引用方式
GB/T 7714
Xiao X,Zhang YJ,Wang ZG,et al. Experimental Studies on Three-Dimensional Fluorescence Spectral of Mineral Oil in Ethanol[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2010,30.
APA 肖雪.,张玉钧.,王志刚.,金丹.,殷高方.,...&刘文清.(2010).Experimental Studies on Three-Dimensional Fluorescence Spectral of Mineral Oil in Ethanol.SPECTROSCOPY AND SPECTRAL ANALYSIS,30.
MLA 肖雪,et al."Experimental Studies on Three-Dimensional Fluorescence Spectral of Mineral Oil in Ethanol".SPECTROSCOPY AND SPECTRAL ANALYSIS 30(2010).

入库方式: OAI收割

来源:合肥物质科学研究院

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