A novel silicon nanoparticles-infilled capsule prepared by an oil-in-water emulsion strategy for high-performance Li-ion battery anodes
文献类型:期刊论文
作者 | Wu, Yong3; Han, Tianli3; Zhou, Ting3; Qiao, Xue3; Chen, Xi2; Zhou, Ping1; Liu, Jinyun3 |
刊名 | NANOTECHNOLOGY |
出版日期 | 2020-08-14 |
卷号 | 31 |
ISSN号 | 0957-4484 |
关键词 | silicon nanoparticles capsules yolk-shell nanostructures secondary batteries |
DOI | 10.1088/1361-6528/ab90b9 |
通讯作者 | Han, Tianli(hantianli@ahnu.edu.cn) |
英文摘要 | Conventional approaches for preparing yolk-shell nanostructures require complicated procedures such as multi-step coatings and template removal. Herein, we present a new and general strategy for making yolk-shell nanocomposites based on an oil-in-water emulsion system. As a demonstrating case, silicon nanoparticles were dispersed in an oil phase which was in an oil-in-water emulsion; then the oil/water interface wasin-situpolymerized to form microcapsules. After carbonization, the shell of microcapsules was formed. The Li-ion battery anodes based on the microcapsules exhibit a good electrochemical performance including stable capacity and high rate-performance. The capacity remains 1100 mAh g(-1)after 500 cycles at a current density of 1.9 A g(-1), along with a Coulombic efficiency of 99.9%. In addition, the method presented here is general, which is applicable for the synthesis of many yolk shell-structured nanocomposites. |
WOS关键词 | YOLK-SHELL STRUCTURE ; CYCLING STABILITY ; CARBON SHELL ; AT-CARBON ; LITHIUM ; NANOSHEETS ; COMPOSITE ; CATALYST ; SPHERES ; ROBUST |
资助项目 | Science and Technology Major Project of Anhui Province[18030901093] ; Key Research and Development Program of Wuhu[2019YF07] ; Natural Science Research Project for Universities in Anhui Province[KJ2018ZD034] ; Natural Science Research Project for Universities in Anhui Province[KJ2019A0502] ; Anhui Provincial Program for Innovation and Entrepreneurship of Returnees from Overseas[2019LCX005] ; Foundation of Anhui Laboratory of Molecule-Based Materials[FZJ19014] |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Physics |
语种 | 英语 |
出版者 | IOP PUBLISHING LTD |
WOS记录号 | WOS:000540854900001 |
资助机构 | Science and Technology Major Project of Anhui Province ; Key Research and Development Program of Wuhu ; Natural Science Research Project for Universities in Anhui Province ; Anhui Provincial Program for Innovation and Entrepreneurship of Returnees from Overseas ; Foundation of Anhui Laboratory of Molecule-Based Materials |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/103039] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Han, Tianli |
作者单位 | 1.Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Peoples R China 2.Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA 3.Anhui Normal Univ, Key Lab Funct Mol Solids, Anhui Lab Based Mol Mat, Minist Educ,Coll Chem & Mat Sci, Wuhu 241000, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Yong,Han, Tianli,Zhou, Ting,et al. A novel silicon nanoparticles-infilled capsule prepared by an oil-in-water emulsion strategy for high-performance Li-ion battery anodes[J]. NANOTECHNOLOGY,2020,31. |
APA | Wu, Yong.,Han, Tianli.,Zhou, Ting.,Qiao, Xue.,Chen, Xi.,...&Liu, Jinyun.(2020).A novel silicon nanoparticles-infilled capsule prepared by an oil-in-water emulsion strategy for high-performance Li-ion battery anodes.NANOTECHNOLOGY,31. |
MLA | Wu, Yong,et al."A novel silicon nanoparticles-infilled capsule prepared by an oil-in-water emulsion strategy for high-performance Li-ion battery anodes".NANOTECHNOLOGY 31(2020). |
入库方式: OAI收割
来源:合肥物质科学研究院
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