Fabrication of hierarchically porous NH2-MIL-53/wood-carbon hybrid membrane for highly effective and selective sequestration of Pb2+
文献类型：期刊论文
| 作者 | Gu, Yue1,3; Wang, Yongchuang1,3; Li, Huaimeng1,3; Qin, Wenxiu1; Zhang, Haimin1; Wang, Guozhong1 ; Zhang, Yunxia1; Zhao, Huijun1,2
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| 刊名 | CHEMICAL ENGINEERING JOURNAL
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| 出版日期 | 2020-05-01 |
| 卷号 | 387 |
| 关键词 | NH2-MIL-53/WC Hybrid membrane Pb2+ Selective adsorption Continuous-flow |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2020.124141 |
| 通讯作者 | Zhang, Yunxia(yxzhang@issp.ac.cn) |
| 英文摘要 | Designing the desirable architecture for highly efficient sequestration of heavy metal ions is of paramount importance to ensure water safety. Herein, highly dense cuboid-like NH2-MIL-53 crystals have been in-situ immobilized on porous wood-carbon (WC) substrate (denoted as NH2-MIL-53/WC) based on a self-sacrificial template strategy. Benefiting from the perfect integration of unique 3D hierarchical pore structures, abundant binding sites, and specific sorption affinity of amino functional groups in NH2-MIL-53 toward Pb2+, the resulting NH2-MIL-53/WC hybrid membrane exhibits exceptional Pb2+ decontamination capability in terms of high uptake capacity, fast removal kinetics and superior selectivity in the presence of competing ions. Meanwhile, the macroscopic-sized monolithic shape is competent for facile separation, overcoming the inherent limitations of conventional nanosorbents. Furthermore, the as-fabricated monolithic membrane can be further assembled into a home-made filter system for continuous-flow wastewater purification, accompanied by an efficient treatment capacity of 2200 kg wastewater (spiked with 10 ppm Pb2+) per kg sorbent, while restricting the Pb2+ level in the effluent below the World Health Organization (WHO) limit (10 ppb). Such intriguing Pb2+ sequestration performance in both static and flowing states render the proposed NH2-MIL-53/WC hybrid membrane to hold huge prospects for the practical wastewater remediation. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; EFFICIENT REMOVAL ; FACILE FABRICATION ; SANDWICH-STRUCTURE ; WASTE-WATER ; ADSORPTION ; COMPOSITE ; BIOCHAR ; IONS ; WOOD |
| 资助项目 | National Key R&D Program of China[2017YFA0207202] ; National Natural Science Foundation of China[51572263] ; National Natural Science Foundation of China[51772299] ; National Natural Science Foundation of China[41701259] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000527331600119 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/103449]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Zhang, Yunxia |
| 作者单位 | 1.Chinese Acad Sci, Ctr Environm & Energy Nanomat, Anhui Key Lab Nanomat & Nanotechnol, Inst Solid State Phys,Key Lab Mat Phys,CAS Ctr Ex, Hefei 230031, Peoples R China 2.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Gold Coast, Qld 4222, Australia 3.Univ Sci & Technol China, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Yue,Wang, Yongchuang,Li, Huaimeng,et al. Fabrication of hierarchically porous NH2-MIL-53/wood-carbon hybrid membrane for highly effective and selective sequestration of Pb2+[J]. CHEMICAL ENGINEERING JOURNAL,2020,387. |
| APA | Gu, Yue.,Wang, Yongchuang.,Li, Huaimeng.,Qin, Wenxiu.,Zhang, Haimin.,...&Zhao, Huijun.(2020).Fabrication of hierarchically porous NH2-MIL-53/wood-carbon hybrid membrane for highly effective and selective sequestration of Pb2+.CHEMICAL ENGINEERING JOURNAL,387. |
| MLA | Gu, Yue,et al."Fabrication of hierarchically porous NH2-MIL-53/wood-carbon hybrid membrane for highly effective and selective sequestration of Pb2+".CHEMICAL ENGINEERING JOURNAL 387(2020). |
入库方式： OAI收割
来源：合肥物质科学研究院
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